Literature DB >> 25354017

Proton dynamics in oxides: insight into the mechanics of proton conduction from quasielastic neutron scattering.

Maths Karlsson1.   

Abstract

This article is concerned with the use of quasielastic neutron scattering as a technique for investigation of the dynamical properties of proton conducting oxides. Currently, the main interest in these materials comes from their promise as electrolytes in future electrochemical devices and particularly through their use as electrolytes in next-generation, intermediate-temperature, fuel cells. However, the realization of such devices depends critically on the development of new, more highly proton conducting oxides. Such a development depends on increasing the current understanding of proton conduction in oxides and for this purpose quasielastic neutron scattering is an important mean. The aim of this article is to introduce the non-specialist reader to the basic principles of quasielastic neutron scattering, its advantages and disadvantages, to summarize the work that has been done on proton conducting oxides using this technique, as well as to discuss future opportunities within this field of research.

Year:  2015        PMID: 25354017     DOI: 10.1039/c4cp04112g

Source DB:  PubMed          Journal:  Phys Chem Chem Phys        ISSN: 1463-9076            Impact factor:   3.676


  4 in total

1.  Insight into Design of Improved Oxide Ion Conductors: Dynamics and Conduction Mechanisms in the Bi0.913V0.087O1.587 Solid Electrolyte.

Authors:  Joseph R Peet; Chloe A Fuller; Bernhard Frick; Michael M Koza; Mark R Johnson; Andrea Piovano; Ivana Radosavljevic Evans
Journal:  J Am Chem Soc       Date:  2019-06-13       Impact factor: 15.419

2.  Quasielastic neutron scattering of brucite to analyse hydrogen transport on the atomic scale.

Authors:  Takuo Okuchi; Naotaka Tomioka; Narangoo Purevjav; Kaoru Shibata
Journal:  J Appl Crystallogr       Date:  2018-10-25       Impact factor: 3.304

3.  Highly Efficient Proton Conduction in the Metal-Organic Framework Material MFM-300(Cr)·SO4(H3O)2.

Authors:  Jin Chen; Qingqing Mei; Yinlin Chen; Christopher Marsh; Bing An; Xue Han; Ian P Silverwood; Ming Li; Yongqiang Cheng; Meng He; Xi Chen; Weiyao Li; Meredydd Kippax-Jones; Danielle Crawshaw; Mark D Frogley; Sarah J Day; Victoria García-Sakai; Pascal Manuel; Anibal J Ramirez-Cuesta; Sihai Yang; Martin Schröder
Journal:  J Am Chem Soc       Date:  2022-07-01       Impact factor: 16.383

4.  Thermoelectric Behavior of BaZr0.9Y0.1O3-d Proton Conducting Electrolyte.

Authors:  Dmitry Tsvetkov; Ivan Ivanov; Dmitry Malyshkin; Vladimir Sereda; Andrey Zuev
Journal:  Membranes (Basel)       Date:  2019-09-13
  4 in total

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