Literature DB >> 25322967

Redox-induced fluoride ligand dissociation stabilized by intramolecular hydrogen bonding.

Cameron M Moore1, Nathaniel K Szymczak.   

Abstract

Chemical reduction of a tripodal Cu(II)-F complex containing pendent hydroxyl groups results in the partial dissociation of a F(-) ligand from Cu. The resulting Cu(I) complex is characterized as containing an outer sphere F(-) anion 'captured' by hydrogen bonds. The pendent hydroxyl groups were found to be crucial for reductive stability.

Entities:  

Year:  2015        PMID： 25322967     DOI： 10.1039/c4cc06832g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  8 in total

1.  Hydrazine Capture and N-N Bond Cleavage at Iron Enabled by Flexible Appended Lewis Acids.

Authors:  John J Kiernicki; Matthias Zeller; Nathaniel K Szymczak
Journal:  J Am Chem Soc       Date:  2017-12-11       Impact factor: 15.419

2.  Nitrite reduction by copper through ligand-mediated proton and electron transfer.

Authors:  Cameron M Moore; Nathaniel K Szymczak
Journal:  Chem Sci       Date:  2015-04-14       Impact factor: 9.825

3.  Hydrogen Bonds Dictate O2 Capture and Release within a Zinc Tripod.

Authors:  Eric W Dahl; John J Kiernicki; Matthias Zeller; Nathaniel K Szymczak
Journal:  J Am Chem Soc       Date:  2018-08-03       Impact factor: 15.419

4.  Phenylamino derivatives of tris(2-pyridylmethyl)amine: hydrogen-bonded peroxodicopper complexes.

Authors:  E W Dahl; H T Dong; N K Szymczak
Journal:  Chem Commun (Camb)       Date:  2018-01-23       Impact factor: 6.222

5.  Hydrogen Bonds Dictate the Coordination Geometry of Copper: Characterization of a Square-Planar Copper(I) Complex.

Authors:  Eric W Dahl; Nathaniel K Szymczak
Journal:  Angew Chem Int Ed Engl       Date:  2016-01-28       Impact factor: 15.336

6.  Hydrogen-bonded nickel(I) complexes.

Authors:  Jessica R Wilson; Matthias Zeller; Nathaniel K Szymczak
Journal:  Chem Commun (Camb)       Date:  2021-01-26       Impact factor: 6.222

7.  Tuning ligand field strength with pendent Lewis acids: access to high spin iron hydrides.

Authors:  John J Kiernicki; James P Shanahan; Matthias Zeller; Nathaniel K Szymczak
Journal:  Chem Sci       Date:  2019-05-07       Impact factor: 9.825

8.  Direct Aerobic Generation of a Ferric Hydroperoxo Intermediate Via a Preorganized Secondary Coordination Sphere.

Authors:  Kate A Jesse; Sophie W Anferov; Kelsey A Collins; Juan A Valdez-Moreira; Maia E Czaikowski; Alexander S Filatov; John S Anderson
Journal:  J Am Chem Soc       Date:  2021-10-26       Impact factor: 15.419
  8 in total

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