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Literature DB >> 25294095

An M12(L(1))12(L(2))12 cantellated tetrahedron: a case study on mixed-ligand self-assembly.

Abstract

In the self-assembly of Pd(II) ions and two different, but similarly shaped, ligands (1 and 2), neither random mixing nor self-sorting of the two ligands into two unmixed structures was observed. Instead a mixed, yet sorted, Pd12 (1)12 (2)12 cantellated tetrahedron (and its pseudoisomer) was selectively formed, thus revealing a fine example of intramolecular self-sorting. A case study showed that a homothetic ratio of >2 is necessary to observe cantellated tetrahedra.

Entities: Chemical

Keywords: ligand effects; palladium; self-assembly; self-sorting

Year: 2014 PMID： 25294095 DOI： 10.1002/anie.201408652

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

14 in total

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2. High fidelity sorting of remarkably similar components via metal-mediated assembly.

Authors: Lauren R Holloway; Michael C Young; Gregory J O Beran; Richard J Hooley
Journal: Chem Sci Date: 2015-06-02 Impact factor: 9.825

3. Tellurite-Squarate Driven Assembly of a New Family of Nanoscale Clusters Based on (Mo₂ O₂ S₂ )².

Authors: Jamie W Purcell; Haralampos N Miras; De-Liang Long; Panagiota Markopoulou; Leroy Cronin
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4. Homochiral Emissive Λ₈ - and Δ₈ -[Ir₈ Pd₄ ]¹⁶⁺ Supramolecular Cages.

Authors: Diego Rota Martir; Daniel Escudero; Denis Jacquemin; David B Cordes; Alexandra M Z Slawin; Herbert A Fruchtl; Stuart L Warriner; Eli Zysman-Colman
Journal: Chemistry Date: 2017-09-12 Impact factor: 5.236

5. Adaptive self-assembly and induced-fit transformations of anion-binding metal-organic macrocycles.

Authors: Ting Zhang; Li-Peng Zhou; Xiao-Qing Guo; Li-Xuan Cai; Qing-Fu Sun
Journal: Nat Commun Date: 2017-06-16 Impact factor: 14.919

6. Assembly of inorganic [Mo₂S₂O₂]²⁺ panels connected by selenite anions to nanoscale chalcogenide-polyoxometalate clusters.

Authors: Hong-Ying Zang; Jia-Jia Chen; De-Liang Long; Leroy Cronin; Haralampos N Miras
Journal: Chem Sci Date: 2016-02-25 Impact factor: 9.825

An M12(L(1))12(L(2))12 cantellated tetrahedron: a case study on mixed-ligand self-assembly.

Review 1. Beyond Platonic: How to Build Metal-Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes.

2. High fidelity sorting of remarkably similar components via metal-mediated assembly.

3. Tellurite-Squarate Driven Assembly of a New Family of Nanoscale Clusters Based on (Mo₂ O₂ S₂ )².

4. Homochiral Emissive Λ₈ - and Δ₈ -[Ir₈ Pd₄ ]¹⁶⁺ Supramolecular Cages.

5. Adaptive self-assembly and induced-fit transformations of anion-binding metal-organic macrocycles.

6. Assembly of inorganic [Mo₂S₂O₂]²⁺ panels connected by selenite anions to nanoscale chalcogenide-polyoxometalate clusters.

7. Integrative self-sorting of coordination cages based on 'naked' metal ions.

8. Donor-Site-Directed Rational Assembly of Heteroleptic cis-[Pd₂ L₂ L'₂ ] Coordination Cages from Picolyl Ligands.

9. Mixed-Ligand Metal-Organic Frameworks and Heteroleptic Coordination Cages as Multifunctional Scaffolds-A Comparison.

10. Tunable Fullerene Affinity of Cages, Bowls and Rings Assembled by Pd^II Coordination Sphere Engineering.