Literature DB >> 25249920

6-Amino-3-methyl-4-(3,4,5-tri-meth-oxy-phen-yl)-2,4-di-hydro-pyrano[2,3-c]pyrazole-5-carbo-nitrile.

Naresh Sharma1, Goutam Brahmachari2, Bubun Banerjee2, Rajni Kant1, Vivek K Gupta1.   

Abstract

In the title compound, C17H18N4O4, the dihedral angle between the n class="Chemical">benzene ring and 2,4-di-hydro-pyrano[2,3-c]pyrazole ring system is 89.41 (7)°. The pyran moiety adopts a strongly flattened boat conformation. In the crystal, mol-ecules are linked by N-H⋯N, N-H⋯O, C-H⋯N and C-H⋯O hydrogen bonds into an infinite two-dimensional network parallel to (110). There are π-π inter-actions between the pyrazole rings in neighbouring layers [centroid-centroid distance = 3.621 (1) Å].

Entities:  

Keywords:  crystal structure

Year:  2014        PMID: 25249920      PMCID: PMC4158517          DOI: 10.1107/S1600536814015670

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


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1.  Crystal structure of 6-amino-4-(3-bromo-4-meth-oxy-phen-yl)-3-methyl-2,4-di-hydro-pyrano[2,3-c]pyrazole-5-carbo-nitrile dimethyl sulfoxide monosolvate.

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Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-06-06
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