Literature DB >> 25138494

Aromatic polyhedral hydroxyborates: bridging boron oxides and boron hydrides.

T Peymann1, A Herzog, C B Knobler, M F Hawthorne.   

Abstract

No explosion, but per-B-hydroxylation occurs if the icosahedral boron hydrides [closo-B12 H12 ](2-) (see picture), [closo-CB11 H12 ](-) , or closo-1,12-(CH2 OH)2 -1,12-C2 B10 H10 are refluxed in 30 % hydrogen peroxide. Thus, the three isoelectronic species [closo-B12 (OH)12 ](2-) , [closo-1-H-1-CB11 (OH)11 ](-) , and closo-1,12-H2 -1,12-C2 B10 (OH)10 were obtained. ○=BH, ○=BOH.
Copyright © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Borates; Boron; Clusters; Hydroxylation; Polyhedral borane anions

Year:  1999        PMID： 25138494     DOI： 10.1002/(SICI)1521-3773(19990419)38:8<1061::AID-ANIE1061>3.0.CO;2-B

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  5 in total

1.  Synthesis and Applications of Perfunctionalized Boron Clusters.

Authors:  Jonathan C Axtell; Liban M A Saleh; Elaine A Qian; Alex I Wixtrom; Alexander M Spokoyny
Journal:  Inorg Chem       Date:  2018-02-21       Impact factor: 5.165

2.  Rapid Synthesis of Redox-Active Dodecaborane B12(OR)12 Clusters Under Ambient Conditions.

Authors:  Alex I Wixtrom; Yanwu Shao; Dahee Jung; Charles W Machan; Shaunt N Kevork; Elaine A Qian; Jonathan C Axtell; Saeed I Khan; Clifford P Kubiak; Alexander M Spokoyny
Journal:  Inorg Chem Front       Date:  2016-03-03       Impact factor: 6.569

3.  Pd(ii)-catalyzed synthesis of bifunctionalized carboranes via cage B-H activation of 1-CH2NH2-o-carboranes.

Authors:  Xiaolei Zhang; Hong Yan
Journal:  Chem Sci       Date:  2018-03-27       Impact factor: 9.825

Review 4.  Electrochemical Cage Activation of Carboranes.

Authors:  Long Yang; Zi-Jing Zhang; Becky Bongsuiru Jei; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-25       Impact factor: 16.823

5.  Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling.

Authors:  Stephan Hagspiel; Merle Arrowsmith; Felipe Fantuzzi; Alexander Hermann; Valerie Paprocki; Regina Drescher; Ivo Krummenacher; Holger Braunschweig
Journal:  Chem Sci       Date:  2019-11-25       Impact factor: 9.825
  5 in total

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