Literature DB >> 25123398

Activator-free palladium-catalyzed silylation of aryl chlorides with silylsilatranes.

Yutaro Yamamoto1, Hiroshi Matsubara, Kei Murakami, Hideki Yorimitsu, Atsuhiro Osuka.   

Abstract

The palladium-catalyzed silylation of aryl chlorides with silylsilatranes proceeds under activator-free conditions; hence, wide functional group compatibility is displayed and boryl and siloxy groups are able to survive. Experimental and computational studies revealed that smooth transmetalation from the silylsilatrane to the arylpalladium chloride is facilitated by strong interaction between the Lewis acidic silicon and the chloride.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  aryl chlorides; palladium; silylation; silylsilatranes; transmetalation

Year:  2014        PMID： 25123398     DOI： 10.1002/asia.201402595

Source DB:  PubMed          Journal:  Chem Asian J        ISSN： 1861-471X


  6 in total

Review 1.  Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis.

Authors:  Bogdan Marciniec; Cezary Pietraszuk; Piotr Pawluć; Hieronim Maciejewski
Journal:  Chem Rev       Date:  2021-12-30       Impact factor: 60.622

2.  Oligosilanylsilatranes.

Authors:  Mohammad Aghazadeh Meshgi; Judith Baumgartner; Christoph Marschner
Journal:  Organometallics       Date:  2015-07-28       Impact factor: 3.876

3.  Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives.

Authors:  Mohammad Aghazadeh Meshgi; Judith Baumgartner; Viatcheslav V Jouikov; Christoph Marschner
Journal:  Organometallics       Date:  2016-12-20       Impact factor: 3.876

4.  Tuning the Si-N Interaction in Metalated Oligosilanylsilatranes.

Authors:  Mohammad Aghazadeh Meshgi; Rainer Zitz; Małgorzata Walewska; Judith Baumgartner; Christoph Marschner
Journal:  Organometallics       Date:  2017-03-21       Impact factor: 3.876

5.  Hypercoordinated Oligosilanes Based on Aminotrisphenols.

Authors:  Mohammad Aghazadeh Meshgi; Kirill V Zaitsev; Mikhail V Vener; Andrei V Churakov; Judith Baumgartner; Christoph Marschner
Journal:  ACS Omega       Date:  2018-08-31

6.  Oligosilanylated Silocanes.

Authors:  Mohammad Aghazadeh Meshgi; Alexander Pöcheim; Judith Baumgartner; Viatcheslav V Jouikov; Christoph Marschner
Journal:  Molecules       Date:  2021-01-05       Impact factor: 4.411
  6 in total

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