Joshua H Palmer1, Gerard Parkin. 1. Department of Chemistry, Columbia University, New York, New York 10027, USA. parkin@columbia.edu.
Abstract
The tris(2-mercapto-1-methylbenzimidazolyl)hydroborato cadmium complexes, {[Tm(MeBenz)]Cd(μ-Cl)}2 and [Tm(MeBenz)]CdI, have been synthesized via the reactions of [Tm(MeBenz)]K with CdCl2 and CdI2, respectively. While X-ray diffraction studies demonstrate that the iodide derivative, [Tm(MeBenz)]CdI, is a monomer, the chloride derivative, {[Tm(MeBenz)]Cd(μ-Cl)}2, exists as a dimer, which is unprecedented for Group 12 [Tm(R)]MX (X = Cl, Br, I) compounds. Furthermore, the cadmium centers of {[Tm(MeBenz)]Cd(μ-Cl)}2 are trigonal bipyramidal, which is an uncommon motif for cadmium complexes with a [S3Cl2] coordination sphere.
The tris(2-mercapto-1-methylbenzimidazolyl)hydroborato cadmium complexes, n class="Chemical">{[Tm(MeBenz)]Cd(μ-Cl)}2 and [Tm(MeBenz)]CdI, have been synthesized via the reactions of [Tm(MeBenz)]K with CdCl2 and CdI2, respectively. While X-ray diffraction studies demonstrate that the iodide derivative, [Tm(MeBenz)]CdI, is a monomer, the chloride derivative, {[Tm(MeBenz)]Cd(μ-Cl)}2, exists as a dimer, which is unprecedented for Group 12 [Tm(R)]MX (X = Cl, Br, I) compounds. Furthermore, the cadmium centers of {[Tm(MeBenz)]Cd(μ-Cl)}2 are trigonal bipyramidal, which is an uncommon motif for cadmium complexes with a [S3Cl2] coordination sphere.
Authors: Ava Kreider-Mueller; Patrick J Quinlivan; Yi Rong; Jonathan S Owen; Gerard Parkin Journal: J Organomet Chem Date: 2015-09-01 Impact factor: 2.369