Literature DB >> 25007289

Dihydrolevoglucosenone (Cyrene) as a bio-based alternative for dipolar aprotic solvents.

James Sherwood1, Mario De bruyn, Andri Constantinou, Laurianne Moity, C Rob McElroy, Thomas J Farmer, Tony Duncan, Warwick Raverty, Andrew J Hunt, James H Clark.   

Abstract

Dihydrolevoglucosenone (Cyrene) is a bio-based molecule, derived in two simple steps from cellulose, which demonstrates significant promise as a dipolar aprotic solvent. The dipolarity of dihydrolevoglucosenone is similar to NMP, DMF and sulpholane. Dihydrolevoglucosenone demonstrates similar performance to NMP in a fluorination reaction and the Menschutkin reaction.

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Year:  2014        PMID： 25007289     DOI： 10.1039/c4cc04133j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  18 in total

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Journal:  ACS Sustain Chem Eng       Date:  2019-07-03       Impact factor: 8.198

9.  Synergetic Effect of Brønsted/Lewis Acid Sites and Water on the Catalytic Dehydration of Glucose to 5-Hydroxymethylfurfural by Heteropolyacid-Based Ionic Hybrids.

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10.  Geminal Diol of Dihydrolevoglucosenone as a Switchable Hydrotrope: A Continuum of Green Nanostructured Solvents.

Authors:  Mario De Bruyn; Vitaliy L Budarin; Antonio Misefari; Seishi Shimizu; Heather Fish; Martin Cockett; Andrew J Hunt; Heike Hofstetter; Bert M Weckhuysen; James H Clark; Duncan J Macquarrie
Journal:  ACS Sustain Chem Eng       Date:  2019-03-15       Impact factor: 8.198
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