| Literature DB >> 24861787 |
Jing Lu1, Wenfen Zhang1, Yanhao Zhang1, Wenjie Zhao2, Kai Hu3, Ajuan Yu1, Pu Liu4, Yangjie Wu1, Shusheng Zhang5.
Abstract
In the present paper, a new calix[4]arene derivatized chitosan bonded stationary phase (CCS4) for high performance liquid chromatography (HPLC) was synthesized and characterized. Its chromatographic performance and retention mechanism were evaluated in reversed-phase mode compared with ODS using different solute probes including mono-substituted benzenes, phenols and nucleosides. The results showed that CCS4 stationary phase could provide various interactions with solutes, such as hydrophobic, hydrophilic, π-π, and inclusion interactions. It could perform the mixed-mode separation including RP and HILIC.Entities:
Keywords: Calix[4]arene; Chitosan; HILIC; Mixed-mode separation; RPLC; Stationary phase
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Year: 2014 PMID: 24861787 DOI: 10.1016/j.chroma.2014.05.021
Source DB: PubMed Journal: J Chromatogr A ISSN: 0021-9673 Impact factor: 4.759