Literature DB >> 24853979

Synthesis and ligand-based reduction chemistry of boron difluoride complexes with redox-active formazanate ligands.

M-C Chang1, E Otten.   

Abstract

Mono(formazanate) boron difluoride complexes (LBF2), which show remarkably facile and reversible ligand-based redox-chemistry, were synthesized by transmetallation of bis(formazanate) zinc complexes with boron trifluoride. The one-electron reduction product [LBF2](-)[Cp2Co](+) and a key intermediate for the transmetallation reaction, the six-coordinate zinc complex (L(BF3))2Zn were isolated and fully characterized.

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Year:  2014        PMID： 24853979     DOI： 10.1039/c4cc03244f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Alkali Cation Effects on Redox-Active Formazanate Ligands in Iron Chemistry.

Authors:  Daniel L J Broere; Brandon Q Mercado; Eckhard Bill; Kyle M Lancaster; Stephen Sproules; Patrick L Holland
Journal:  Inorg Chem       Date:  2018-04-09       Impact factor: 5.165

2.  Formazanate boron difluoride dyes: discrepancies between TD-DFT and wavefunction descriptions.

Authors:  Adèle D Laurent; Edwin Otten; Boris Le Guennic; Denis Jacquemin
Journal:  J Mol Model       Date:  2016-10-11       Impact factor: 1.810

3.  Reversible Ligand-Centered Reduction in Low-Coordinate Iron Formazanate Complexes.

Authors:  Daniël L J Broere; Brandon Q Mercado; James T Lukens; Avery C Vilbert; Gourab Banerjee; Hannah M C Lant; Shin Hee Lee; Eckhard Bill; Stephen Sproules; Kyle M Lancaster; Patrick L Holland
Journal:  Chemistry       Date:  2018-06-07       Impact factor: 5.236

4.  Arylazoindazole Photoswitches: Facile Synthesis and Functionalization via SNAr Substitution.

Authors:  Raquel Travieso-Puente; Simon Budzak; Juan Chen; Peter Stacko; Johann T B H Jastrzebski; Denis Jacquemin; Edwin Otten
Journal:  J Am Chem Soc       Date:  2017-02-24       Impact factor: 15.419

5.  Reactivity of Two-Electron-Reduced Boron Formazanate Compounds with Electrophiles: Facile N-H/N-C Bond Homolysis Due to the Formation of Stable Ligand Radicals.

Authors:  Ranajit Mondol; Edwin Otten
Journal:  Inorg Chem       Date:  2018-02-15       Impact factor: 5.165

6.  Reversible On/Off Switching of Lactide Cyclopolymerization with a Redox-Active Formazanate Ligand.

Authors:  Folkert de Vries; Edwin Otten
Journal:  ACS Catal       Date:  2022-03-21       Impact factor: 13.084

7.  Neutral Formazan Ligands Bound to the fac-(CO)3Re(I) Fragment: Structural, Spectroscopic, and Computational Studies.

Authors:  Liliana Capulín Flores; Lucas A Paul; Inke Siewert; Remco Havenith; Noé Zúñiga-Villarreal; Edwin Otten
Journal:  Inorg Chem       Date:  2022-08-15       Impact factor: 5.436
  7 in total

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