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Literature DB >> 24824195

A method for the selective hydrogenation of alkenyl halides to alkyl halides.

Sandra M King¹, Xiaoshen Ma, Seth B Herzon.

Abstract

A general method for the selective hydrogenation of alkenyl halides to alkyl halides is described. Fluoro, chloro, bromo, iodo, and gem-dihaloalkenes are viable substrates for the transformation. The selectivity of the hydrogenation is consistent with reduction by a hydrogen atom transfer pathway.

Entities: Chemical

Year: 2014 PMID： 24824195 DOI： 10.1021/ja502885c

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

27 in total

1. The High Chemofidelity of Metal-Catalyzed Hydrogen Atom Transfer.

Authors: Samantha A Green; Steven W M Crossley; Jeishla L M Matos; Suhelen Vásquez-Céspedes; Sophia L Shevick; Ryan A Shenvi
Journal: Acc Chem Res Date: 2018-11-08 Impact factor: 22.384

2. Selective Cobalt-Catalyzed Reduction of Terminal Alkenes and Alkynes Using (EtO)₂Si(Me)H as a Stoichiometric Reductant.

Authors: Balaram Raya; Souvagya Biswas; T V RajanBabu
Journal: ACS Catal Date: 2016-08-12 Impact factor: 13.084

A method for the selective hydrogenation of alkenyl halides to alkyl halides.

1. The High Chemofidelity of Metal-Catalyzed Hydrogen Atom Transfer.

2. Selective Cobalt-Catalyzed Reduction of Terminal Alkenes and Alkynes Using (EtO)₂Si(Me)H as a Stoichiometric Reductant.

3. Twelve-Step Asymmetric Synthesis of (-)-Nodulisporic Acid C.

4. Roles of Iron Complexes in Catalytic Radical Alkene Cross-Coupling: A Computational and Mechanistic Study.

5. Synthesis and Study of the Antimalarial Cardamom Peroxide.

6. Ph(i-PrO)SiH2: An Exceptional Reductant for Metal-Catalyzed Hydrogen Atom Transfers.

7. Metal-free Regioselective Hydrochlorination of Unactivated Alkenes via a Combined Acid Catalytic System.

Review 8. Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities.

9. Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins.

10. A Concise Approach to Paxilline Indole Diterpenes.