Literature DB >> 24803325

Azobenzene-functionalized metal-organic polyhedra for the optically responsive capture and release of guest molecules.

Jinhee Park1, Lin-Bing Sun, Ying-Pin Chen, Zachary Perry, Hong-Cai Zhou.   

Abstract

Stimuli-responsive metal-organic polyhedra (srMOPs) functionalized with azobenzene showed UV-irradiation-induced isomerization from the insoluble trans-srMOP to the soluble cis-srMOP, whereas irradiation with blue light reversed this process. Guest molecules were trapped and released upon cis-to-trans and trans-to-cis isomerization of the srMOPs, respectively. This study provides a new direction in the ever-diversifying field of MOPs, while laying the groundwork for a new class of optically responsive materials.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  azo compounds; host-guest systems; metal-organic polyhedra; optically responsive materials; stimuli-responsive solubility

Mesh：

Substances：

Year:  2014        PMID： 24803325     DOI： 10.1002/anie.201310211

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  20 in total

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3.  Synthesis of Functionalized Azobiphenyl- and Azoterphenyl- Ditopic Linkers: Modular Building Blocks for Photoresponsive Smart Materials.

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Journal:  Adv Mater       Date:  2019-01-31       Impact factor: 30.849

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Authors:  Wei-Chao Song; Xun-Zhe Cui; Zhong-Yi Liu; En-Cui Yang; Xiao-Jun Zhao
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Authors:  Seán T J Ryan; Jesús Del Barrio; Reynier Suardíaz; Daniel F Ryan; Edina Rosta; Oren A Scherman
Journal:  Angew Chem Int Ed Engl       Date:  2016-10-28       Impact factor: 15.336

8.  Reversible disassembly of metallasupramolecular structures mediated by a metastable-state photoacid.

Authors:  Suzanne M Jansze; Giacomo Cecot; Kay Severin
Journal:  Chem Sci       Date:  2018-04-20       Impact factor: 9.825

9.  Stimuli-responsive metal-organic frameworks gated by pillar[5]arene supramolecular switches.

Authors:  Li-Li Tan; Haiwei Li; Yu-Chen Qiu; Dai-Xiong Chen; Xin Wang; Rui-Yi Pan; Yan Wang; Sean Xiao-An Zhang; Bo Wang; Ying-Wei Yang
Journal:  Chem Sci       Date:  2014-12-24       Impact factor: 9.825

10.  Crystal Violet Lactone Salicylaldehyde Hydrazone Zn(II) Complex: a Reversible Photochromic Material both in Solution and in Solid Matrix.

Authors:  Kai Li; Yuanyuan Li; Jing Tao; Lu Liu; Lili Wang; Hongwei Hou; Aijun Tong
Journal:  Sci Rep       Date:  2015-09-28       Impact factor: 4.379
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