Literature DB >> 24801708

Copper-catalyzed regioselective ortho C-H cyanation of vinylarenes.

Yang Yang1, Stephen L Buchwald.   

Abstract

A copper-based catalytic technique for the regioselective ortho C-H cyanation of vinylarenes has been developed. This method provides an effective means for the selective functionalization of vinylarene derivatives. A copper-catalyzed cyanative dearomatization mechanism is proposed to account for the regiochemical course of this reaction.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  CH activation; copper; dearomatization; ligand design; synthetic methods

Mesh：

Substances：

Year:  2014        PMID： 24801708      PMCID： PMC4127133          DOI： 10.1002/anie.201402449

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  39 in total

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