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Literature DB >> 24402371

Versatile ruthenium(II)-catalyzed C-H cyanations of benzamides.

Abstract

Direct cyanations of arenes and heteroarenes bearing only weakly coordinating amides were accomplished using a robust ruthenium(II) catalyst. The user-friendly C(sp(2))-H activation occurred with the assistance of carboxylate with high site-selectivity, excellent functional group tolerance and ample scope.

Entities: Chemical

Year: 2014 PMID： 24402371 DOI： 10.1039/c3cc49502g

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

9 in total

1. Direct C-H Cyanation of Arenes via Organic Photoredox Catalysis.

Authors: Joshua B McManus; David A Nicewicz
Journal: J Am Chem Soc Date: 2017-02-14 Impact factor: 15.419

2. Copper-catalyzed regioselective ortho C-H cyanation of vinylarenes.

Authors: Yang Yang; Stephen L Buchwald
Journal: Angew Chem Int Ed Engl Date: 2014-05-06 Impact factor: 15.336

3. Regio- and Stereospecific 1,3-Allyl Group Transfer Triggered by a Copper-Catalyzed Borylation/ortho-Cyanation Cascade.

Authors: Yang Yang
Journal: Angew Chem Int Ed Engl Date: 2015-10-28 Impact factor: 15.336

9. Synthesis of Nitrile Bearing Acyclic Quaternary Centers through Co(III)-Catalyzed Sequential C-H Bond Addition to Dienes and N-Cyanosuccinimide.

Authors: Sun Dongbang; Jonathan A Ellman
Journal: Angew Chem Int Ed Engl Date: 2020-11-23 Impact factor: 15.336

9 in total

Versatile ruthenium(II)-catalyzed C-H cyanations of benzamides.

1. Direct C-H Cyanation of Arenes via Organic Photoredox Catalysis.

2. Copper-catalyzed regioselective ortho C-H cyanation of vinylarenes.

3. Regio- and Stereospecific 1,3-Allyl Group Transfer Triggered by a Copper-Catalyzed Borylation/ortho-Cyanation Cascade.

4. Ru-catalysed C-H arylation of indoles and pyrroles with boronic acids: scope and mechanistic studies.

5. Metal-Free Direct C-H Cyanation of Alkenes.

Review 6. Recent Advances in Cyanamide Chemistry: Synthesis and Applications.

7. Cobalt-catalyzed C-H cyanations: Insights into the reaction mechanism and the role of London dispersion.

Review 8. Recent advances and perspectives in ruthenium-catalyzed cyanation reactions.

9. Synthesis of Nitrile Bearing Acyclic Quaternary Centers through Co(III)-Catalyzed Sequential C-H Bond Addition to Dienes and N-Cyanosuccinimide.