Literature DB >> 24677611

Carbene-9-BBN ring expansions as a route to intramolecular frustrated Lewis pairs for CO2 reduction.

Tongen Wang, Douglas W Stephan.   

Abstract

Reactions of phosphine-derived carbenes with 9-borabicyclo[3.3.1]nonane (9-BBN) result in ring-expansion reactions to generate novel intramolecular frustrated Lewis pairs (FLPs). These FLPs effect the catalytic reduction of CO2 in the presence of boranes to give BOB and methoxy-borate species.

Entities:  

Year:  2014        PMID： 24677611     DOI： 10.1002/chem.201304870

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  5 in total

1.  Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO2 in the Presence of Silylhalides.

Authors:  Tongtong Wang; Maotong Xu; Andrew R Jupp; Zheng-Wang Qu; Stefan Grimme; Douglas W Stephan
Journal:  Angew Chem Int Ed Engl       Date:  2021-11-03       Impact factor: 16.823

2.  Pincer-Supported Gallium Complexes for the Catalytic Hydroboration of Aldehydes, Ketones and Carbon Dioxide.

Authors:  Lingyu Liu; Siu-Kwan Lo; Cory Smith; Jose M Goicoechea
Journal:  Chemistry       Date:  2021-10-27       Impact factor: 5.020

3.  Transforming atmospheric CO2 into alternative fuels: a metal-free approach under ambient conditions.

Authors:  Samaresh Chandra Sau; Rameswar Bhattacharjee; Pradip Kumar Hota; Pavan K Vardhanapu; Gonela Vijaykumar; R Govindarajan; Ayan Datta; Swadhin K Mandal
Journal:  Chem Sci       Date:  2018-11-30       Impact factor: 9.825

4.  B-B Cleavage and Ring-Expansion of a 1,4,2,3-Diazadiborinine with N-Heterocyclic Carbenes.

Authors:  Torsten Thiess; Soren K Mellerup; Holger Braunschweig
Journal:  Chemistry       Date:  2019-09-19       Impact factor: 5.236

Review 5.  From CO2 activation to catalytic reduction: a metal-free approach.

Authors:  Sreejyothi P; Swadhin K Mandal
Journal:  Chem Sci       Date:  2020-08-20       Impact factor: 9.825
  5 in total

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