Literature DB >> 24659414

Adaptable hetero Diels-Alder networks for fast self-healing under mild conditions.

Kim K Oehlenschlaeger1, Jan O Mueller, Josef Brandt, Stefan Hilf, Albena Lederer, Manfred Wilhelm, Robert Graf, Michelle L Coote, Friedrich G Schmidt, Christopher Barner-Kowollik.   

Abstract

A novel adaptable network based on the reversible hetero Diels-Alder reaction of a cyanodithioester and cyclopentadiene is presented. Reversible between 50-120 °C, the adjustable and self-healing features of the network are evidenced via temperature dependent rheology experiments and repetitive tensile tests whereas the network's chemical structure is explored by temperature dependent (1) H MAS-NMR spectroscopy.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Cyanodithioester; Rheology; Self-healing; hetero Diels-Alder chemistry

Year:  2014        PMID： 24659414     DOI： 10.1002/adma.201306258

Source DB:  PubMed          Journal:  Adv Mater        ISSN： 0935-9648            Impact factor:   30.849


  13 in total

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9.  Low-Temperature Self-Healing of a Microcapsule-Type Protective Coating.

Authors:  Dong-Min Kim; Yu-Jin Cho; Ju-Young Choi; Beom-Jun Kim; Seung-Won Jin; Chan-Moon Chung
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10.  Wavelength-gated photoreversible polymerization and topology control.

Authors:  Hendrik Frisch; Kai Mundsinger; Berwyck L J Poad; Stephen J Blanksby; Christopher Barner-Kowollik
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