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Literature DB >> 24654846

A 3-fold-symmetric ligand based on 2-hydroxypyridine: regulation of ligand binding by hydrogen bonding.

Cameron M Moore¹, David A Quist, Jeff W Kampf, Nathaniel K Szymczak.

Abstract

A tripodal ligand based on 2-hydroxypyridine is presented. Cu-Cl adducts of H3thpa with Cu(I) and Cu(II) provide complexes featuring highly directed, intramolecular hydrogen-bonding interactions. An upper limit for the hydrogen-bonding free energy to Cu(I)-Cl was estimated at ∼18 kcal/mol.

Entities: Chemical

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Year: 2014 PMID： 24654846 DOI： 10.1021/ic5003594

Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165

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Cited

8 in total

1. Modulating the Primary and Secondary Coordination Spheres within a Series of Co^II-OH Complexes.

Authors: Jason R Jones; Joseph W Ziller; A S Borovik
Journal: Inorg Chem Date: 2017-01-17 Impact factor: 5.165

2. Nitrite reduction by copper through ligand-mediated proton and electron transfer.

Authors: Cameron M Moore; Nathaniel K Szymczak
Journal: Chem Sci Date: 2015-04-14 Impact factor: 9.825

3. Ruthenium (II) and Iridium (III) Complexes of N-Heterocyclic Carbene and Pyridinol Derived Bidentate Chelates: Synthesis, Characterization, and Reactivity.

Authors: Deidra L Gerlach; Sopheavy Siek; Dalton B Burks; Jamie M Tesh; Courtney R Thompson; Robert M Vasquez; Nicholas J White; Matthias Zeller; Douglas B Grotjahn; Elizabeth T Papish
Journal: Inorganica Chim Acta Date: 2017-07-01 Impact factor: 2.545

8. Intramolecular N-H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex.

Authors: Jesse V Gavette; Christina M Klug; Lev N Zakharov; Matthew P Shores; Michael M Haley; Darren W Johnson
Journal: Chem Commun (Camb) Date: 2014-07-11 Impact factor: 6.222

8 in total

A 3-fold-symmetric ligand based on 2-hydroxypyridine: regulation of ligand binding by hydrogen bonding.

1. Modulating the Primary and Secondary Coordination Spheres within a Series of Co^II-OH Complexes.

2. Nitrite reduction by copper through ligand-mediated proton and electron transfer.

3. Ruthenium (II) and Iridium (III) Complexes of N-Heterocyclic Carbene and Pyridinol Derived Bidentate Chelates: Synthesis, Characterization, and Reactivity.

4. Spin Interconversion of Heme-Peroxo-Copper Complexes Facilitated by Intramolecular Hydrogen-Bonding Interactions.

5. Uncoupled Redox-Inactive Lewis Acids in the Secondary Coordination Sphere Entice Ligand-Based Nitrite Reduction.

6. Phenylamino derivatives of tris(2-pyridylmethyl)amine: hydrogen-bonded peroxodicopper complexes.

7. Hydrogen Bonds Dictate the Coordination Geometry of Copper: Characterization of a Square-Planar Copper(I) Complex.

8. Intramolecular N-H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex.