| Literature DB >> 24605965 |
Ilke Simsek Turan1, Engin U Akkaya.
Abstract
An enhanced chemiluminescence signal is obtained when electronically triggered dioxetane cleavage is initiated by fluoride-mediated deprotection of the silyl-protecting group, followed by self-immolation via 1,4-quinone-methide rearrangement. The reaction takes place even when the probe is trapped within a PMMA layer on top of a glass plate. In that arrangement, fluoride in aqueous solutions can be detected selectively at low micromolar concentrations.Entities:
Year: 2014 PMID: 24605965 DOI: 10.1021/ol5003412
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005