| Literature DB >> 24496245 |
Ahmed Nuri Kursunlu1, Pervin Deveci1, Ersin Guler1.
Abstract
The aryl-amine containing azacrown ether ring and alkyl-chloro boradiazaindacene (Bodipy) were synthesized by Schiff base condensation. The absorption and emission of a novel Schiff base derivative (based on azacrown-Bodipy ) were performed in presence of different cations such as Zn2+, Ga3+, Pb2+, Hg2+, NH4+ Ca2+, Cu2+, Na+, Ni2+, Cd2+ and Cr3+. The complexation property of the Schiff base was studied in dimethylformamide (DMF) by interacting azacrown-ether group and transition metal nitrates-ammonium chloride. The electrochemical behavior of the Schiff base has also been investigated by cyclic voltammetry. All experimental results indicated that the new compound act as a selective ratiometric chemosensor for Hg2+.Entities:
Keywords: Absorption; Azacrown Ether; Bodipy; Chemosensor; Cyclic voltammetry; Emission
Year: 2013 PMID: 24496245 PMCID: PMC3564662 DOI: 10.1016/j.jlumin.2012.12.020
Source DB: PubMed Journal: J Lumin ISSN: 0022-2313 Impact factor: 3.599