Literature DB >> 24417317

Probing site cooperativity of frustrated phosphine/borane Lewis pairs by a polymerization study.

Tieqi Xu1, Eugene Y-X Chen.   

Abstract

The first highly active phosphine (P)/borane (B) Lewis pair polymerization is promoted unexpectedly by P-B adducts. The P and B site cooperativity is essential for achieving effective polymerization, as shown by this study examining the reactivity of a library of P/B Lewis pairs toward polymerization of a renewable acrylic monomer.

Entities:  

Year:  2014        PMID： 24417317     DOI： 10.1021/ja412445n

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  8 in total

1.  Controlled and Efficient Polymerization of Conjugated Polar Alkenes by Lewis Pairs Based on Sterically Hindered Aryloxide-Substituted Alkylaluminumitle.

Authors:  Xiaojun Wang; Yixin Zhang; Miao Hong
Journal:  Molecules       Date:  2018-02-17       Impact factor: 4.411

2.  Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers.

Authors:  Xing-Yu Sun; Wei-Min Ren; Si-Jie Liu; Yin-Bao Jia; Yi-Ming Wang; Xiao-Bing Lu
Journal:  Molecules       Date:  2018-02-21       Impact factor: 4.411

3.  Proton to hydride umpolung at a phosphonium center via electron relay: a new strategy for main-group based water reduction.

Authors:  Takumi Oishi; Leonardo I Lugo-Fuentes; Yichuan Jing; J Oscar C Jimenez-Halla; Joaquín Barroso-Flores; Masaaki Nakamoto; Yohsuke Yamamoto; Nao Tsunoji; Rong Shang
Journal:  Chem Sci       Date:  2021-11-15       Impact factor: 9.825

4.  Exploring the Reactivity of B-Connected Carboranylphosphines in Frustrated Lewis Pair Chemistry: A New Frame for a Classic System.

Authors:  Jan Schulz; Menyhárt B Sárosi; Evamarie Hey-Hawkins
Journal:  Chemistry       Date:  2022-05-12       Impact factor: 5.020

5.  Zn(OAc)₂-Catalyzing Ring-Opening Polymerization of N-Carboxyanhydrides for the Synthesis of Well-Defined Polypeptides.

Authors:  Yanzhao Nie; Xinmei Zhi; Haifeng Du; Jing Yang
Journal:  Molecules       Date:  2018-03-26       Impact factor: 4.411

6.  Chemoselective Polymerization of Polar Divinyl Monomers with Rare-Earth/Phosphine Lewis Pairs.

Authors:  Pengfei Xu; Lei Wu; Liqiu Dong; Xin Xu
Journal:  Molecules       Date:  2018-02-08       Impact factor: 4.411

7.  Silyl Ketene Acetals/B(C₆F₅)₃ Lewis Pair-Catalyzed Living Group Transfer Polymerization of Renewable Cyclic Acrylic Monomers.

Authors:  Lu Hu; Wuchao Zhao; Jianghua He; Yuetao Zhang
Journal:  Molecules       Date:  2018-03-15       Impact factor: 4.411

8.  Highly Efficient One-Pot Synthesis of COS-Based Block Copolymers by Using Organic Lewis Pairs.

Authors:  Jia-Liang Yang; Xiao-Han Cao; Cheng-Jian Zhang; Hai-Lin Wu; Xing-Hong Zhang
Journal:  Molecules       Date:  2018-01-31       Impact factor: 4.411
  8 in total

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