| Literature DB >> 24392725 |
Peng Li1, Yabing He, Jie Guang, Linghong Weng, John Cong-Gui Zhao, Shengchang Xiang, Banglin Chen.
Abstract
A homochiral microporous hydrogen-bonded organic framework (HOF-2) based on a BINOL derivative has been synthesized and structurally characterized to be a uninodal 6-connected {3(3)5(5)6(6)7} network. This new HOF exhibits not only a permanent porosity with the BET of 237.6 m(2) g(-1) but also, more importantly, a highly enantioselective separation of chiral secondary alcohols with ee value up to 92% for 1-phenylethanol.Entities:
Year: 2014 PMID: 24392725 DOI: 10.1021/ja4129795
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419