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Literature DB >> 24288654

Copper-Catalyzed Carboxylation of Aryl Iodides with Carbon Dioxide.

Abstract

A method for carboxylation of aryl iodides with carbon dioxide has been developed. The reaction employs low loadings of copper iodide/TMEDA or DMEDA catalyst, 1 atm of CO2, DMSO or DMA solvent, and proceeds at 25-70 °C. Good functional group tolerance is observed, with ester, bromide, chloride, fluoride, ether, hydroxy, amino, and ketone functionalities tolerated. Additionally, hindered aryl iodides such as iodomesitylene can also be carboxylated.

Entities: Chemical Gene

Keywords: Carbon dioxide; arenecarboxylic acids; aryl halides; carboxylation; copper catalysis

Year: 2013 PMID： 24288654 PMCID： PMC3839347 DOI： 10.1021/cs400443p

Source DB: PubMed Journal: ACS Catal Impact factor: 13.084

25 in total

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5 in total