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Literature DB >> 23301781

Ni-catalyzed direct carboxylation of benzyl halides with CO2.

Thierry León¹, Arkaitz Correa, Ruben Martin.

Abstract

A novel Ni-catalyzed carboxylation of benzyl halides with CO(2) has been developed. The described carboxylation reaction proceeds under mild conditions (atmospheric CO(2) pressure) at room temperature. Unlike other routes for similar means, our method does not require well-defined and sensitive organometallic reagents and thus is a user-friendly and operationally simple protocol for assembling phenylacetic acids.

Entities: Chemical

Mesh：

Substances：

Year: 2013 PMID： 23301781 DOI： 10.1021/ja311045f

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

24 in total

1. Synthesis of Tetrasubstituted Alkenes by Tandem Metallacycle Formation/Cross-Electrophile Coupling.

Authors: Kirk W Shimkin; John Montgomery
Journal: J Am Chem Soc Date: 2018-05-31 Impact factor: 15.419

2. Breaking Amides using Nickel Catalysis.

Authors: Jacob E Dander; Neil K Garg
Journal: ACS Catal Date: 2017-01-06 Impact factor: 13.084

3. Mechanistic Study of an Improved Ni Precatalyst for Suzuki-Miyaura Reactions of Aryl Sulfamates: Understanding the Role of Ni(I) Species.

Authors: Megan Mohadjer Beromi; Ainara Nova; David Balcells; Ann M Brasacchio; Gary W Brudvig; Louise M Guard; Nilay Hazari; David J Vinyard
Journal: J Am Chem Soc Date: 2017-01-10 Impact factor: 15.419

Ni-catalyzed direct carboxylation of benzyl halides with CO2.

1. Synthesis of Tetrasubstituted Alkenes by Tandem Metallacycle Formation/Cross-Electrophile Coupling.

2. Breaking Amides using Nickel Catalysis.

3. Mechanistic Study of an Improved Ni Precatalyst for Suzuki-Miyaura Reactions of Aryl Sulfamates: Understanding the Role of Ni(I) Species.

4. Well-defined nickel and palladium precatalysts for cross-coupling.

5. Cross-Electrophile Coupling of Unactivated Alkyl Chlorides.

6. Development of an Improved System for the Carboxylation of Aryl Halides through Mechanistic Studies.

7. Copper-Catalyzed Carboxylation of Aryl Iodides with Carbon Dioxide.

8. Nickel(I) Aryl Species: Synthesis, Properties, and Catalytic Activity.

9. Mechanism of Ni-Catalyzed Reductive 1,2-Dicarbofunctionalization of Alkenes.

Review 10. Recent advances in homogeneous nickel catalysis.