Literature DB >> 24285607

Rational design of boradiazaindacene (BODIPY)-based functional molecules.

Monika Gupta1, Soumyaditya Mula, Mrityunjay Tyagi, Tapan K Ghanty, Sushant Murudkar, Alok K Ray, Subrata Chattopadhyay.   

Abstract

Three boradiazaindacene (BODIPY) dyes with different-coloured (greenish-yellow, orange and red) fluorescence and good Stokes shifts were synthesised starting from the greenish-yellow BODIPY dye PM546. The high Stokes shifts of the dyes are due to the release of the steric strain in their excited states relative to that in the highly twisted ground states. One of these compounds might be a useful water-soluble fluorophore, whereas the other two are promising H(+) sensors.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Schiff bases; density functional calculations; dyes/pigments; fluorescence; strained molecules

Mesh:

Substances:

Year:  2013        PMID: 24285607     DOI: 10.1002/chem.201302359

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  2 in total

1.  Synthesis of Functional Fluorescent BODIPY-based Dyes through Electrophilic Aromatic Substitution: Straightforward Approach towards Customized Fluorescent Probes.

Authors:  Giorgio Mirri; Daniël C Schoenmakers; Paul H J Kouwer; Peter Veranič; Igor Muševič; Bogdan Štefane
Journal:  ChemistryOpen       Date:  2016-08-19       Impact factor: 2.911

2.  Further investigation on the nitration of BODIPY with cupric nitrate: crystal structures of 4,4-di-fluoro-1,3,5,7,8-penta-methyl-2-nitro-4-bora-3a,4a-di-aza-s-indacene, 4,4-di-fluoro-3-nitro-8-phenyl-4-bora-3a,4a-di-aza-s-indacene, and 3-chloro-6-ethyl-5,7,8-trimethyl-2-nitro-4,4-diphenyl-4-bora-3a,4a-di-aza-s-indacene.

Authors:  Dhruval J Joshi; Meesook Jun; Lijing Yang; Alan J Lough; Hongbin Yan
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2018-01-09
  2 in total

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