Fraser F Fleming1, Subramanyham Gudipati. 1. Department of Chemistry and Biochemistry, Mellon Hall, Duquesne University, Pittsburgh PA 15282-1530, USA.
Abstract
Metalated nitriles are nucleophilic chameleons whose precise identity is determined by the nature of the metal, the solvent, the temperature, and the structure of the nitrile. The review surveys the different structural types and their cyclization trajectories to show how to selectively tune the metalated nitrile geometry for stereoselective cyclizations to a variety of cis or trans hydrindanes, decalins, and bicyclo[4.3.0]undecanes.
Metalated nitriles are nucleophilic n class="Species">chameleons whose precise identity is determined by the nature of the metal, the solvent, the temperature, and the structure of the nitrile. The review surveys the different structural types and their cyclization trajectories to show how to selectively tune the metalated nitrile geometry for stereoselective cyclizations to a variety of cis or trans hydrindanes, decalins, and bicyclo[4.3.0]undecanes.
Authors: S M Rahman; H Ohno; T Murata; H Yoshino; N Satoh; K Murakami; D Patra; C Iwata; N Maezaki; T Tanaka Journal: J Org Chem Date: 2001-07-13 Impact factor: 4.354
Authors: S M Rahman; H Ohno; T Murata; H Yoshino; N Satoh; K Murakami; D Patra; C Iwata; N Maezaki; T Tanaka Journal: Org Lett Date: 2001-02-22 Impact factor: 6.005