Literature DB >> 24254900

Oxidative cyclization reactions: controlling the course of a radical cation-derived reaction with the use of a second nucleophile.

Alison Redden1, Robert J Perkins, Kevin D Moeller.   

Abstract

Construction of new ring systems: Oxidative cyclizations (see picture; RVC=reticulated vitreous carbon) have been conducted that use two separate intramolecular nucleophiles to trap an enol ether-derived radical cation intermediate. The reactions provide a means for rapidly trapping the radical cation intermediate in a manner that avoids competitive decomposition reactions.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  anodic cyclizations; electrochemistry; radical ions; reactive intermediates

Mesh：

Substances：

Year:  2013        PMID： 24254900      PMCID： PMC4374546          DOI： 10.1002/anie.201308739

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  22 in total

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9.  Direct catalytic anti-markovnikov hydroetherification of alkenols.

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  8 in total

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