Literature DB >> 24243854

Dative bonds in main-group compounds: a case for fewer arrows!

Daniel Himmel1, Ingo Krossing, Andreas Schnepf.   

Abstract

Risky business? The use of dative bonds to describe the electronic structure of main-group compounds has come into vogue in recent years. But where are the limits? When does the description as a dative bond make sense and when is this view misleading? This Essay develops the idea on the basis of current examples.
Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords:  coordinative bonds; covalent bonds; dative bonds; p-block coordination compounds

Year:  2013        PMID： 24243854     DOI： 10.1002/anie.201300461

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  19 in total

1.  Inorganic chemistry: Peculiar boron startles again.

Authors:  Gernot Frenking
Journal:  Nature       Date:  2015-06-18       Impact factor: 49.962

2.  Bonding analysis of telluroketones H₂A = Te (A = C, Si, Ge).

Authors:  Naziah B Jaufeerally; Ponnadurai Ramasami; Paul Jerabek; Gernot Frenking
Journal:  J Mol Model       Date:  2014-09-21       Impact factor: 1.810

3.  Multiple complexation of CO and related ligands to a main-group element.

Authors:  Holger Braunschweig; Rian D Dewhurst; Florian Hupp; Marco Nutz; Krzysztof Radacki; Christopher W Tate; Alfredo Vargas; Qing Ye
Journal:  Nature       Date:  2015-06-18       Impact factor: 49.962

4.  Main Group Redox Catalysis of Organopnictogens: Vertical Periodic Trends and Emerging Opportunities in Group 15.

Authors:  Jeffrey M Lipshultz; Gen Li; Alexander T Radosevich
Journal:  J Am Chem Soc       Date:  2021-01-19       Impact factor: 15.419

5.  Energy Decomposition Analysis Coupled with Natural Orbitals for Chemical Valence and Nucleus-Independent Chemical Shift Analysis of Bonding, Stability, and Aromaticity of Functionalized Fulvenes: A Bonding Insight.

Authors:  Sai Manoj N V T Gorantla; Kartik Chandra Mondal
Journal:  ACS Omega       Date:  2021-07-06

6.  Ambiphilic boron in 1,4,2,5-diazadiborinine.

Authors:  Baolin Wang; Yongxin Li; Rakesh Ganguly; Hajime Hirao; Rei Kinjo
Journal:  Nat Commun       Date:  2016-06-09       Impact factor: 14.919

7.  Metalated Ylides: A New Class of Strong Donor Ligands with Unique Electronic Properties.

Authors:  Lennart T Scharf; Viktoria H Gessner
Journal:  Inorg Chem       Date:  2017-02-27       Impact factor: 5.165

8.  Diverse reactivity of a tricoordinate organoboron L2PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors.

Authors:  Lingbing Kong; Rakesh Ganguly; Yongxin Li; Rei Kinjo
Journal:  Chem Sci       Date:  2015-02-23       Impact factor: 9.825

9.  A comparative study of the coordination behavior of cyclo-P5 and cyclo-As5 ligand complexes towards the trinuclear Lewis acid complex (perfluoro-ortho-phenylene)mercury.

Authors:  Martin Fleischmann; James S Jones; François P Gabbaï; Manfred Scheer
Journal:  Chem Sci       Date:  2014-10-01       Impact factor: 9.825

10.  Preparation and characterization of chemically bonded argon-boroxol ring cation complexes.

Authors:  Jiaye Jin; Wei Li; Yuhong Liu; Guanjun Wang; Mingfei Zhou
Journal:  Chem Sci       Date:  2017-07-17       Impact factor: 9.825
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.