Issues in monitoring wilderness lake chemistry: A case study in the Sawtooth Mountains, Idaho.

A probability-based sample of 48 of the 152 lakes in the Sawtooth Wilderness, Idaho was conducted in summer 1988. Results from this sample were compared to the Environmental Protection Agency's 1985 probability survey of lakes throughout the western United States, which included 17 lakes in the Sawtooth Wilderness. Although methods differed in several respects, including year, season, sampling location within the lakes, holding times, and sample size, general characterization of lake chemistry for the population of lakes in the wilderness based on the two surveys was very similar. The results indicate that general lake characterization in difficult-to-access wilderness areas of the West can be achieved with a modest investment in resources with the use of volunteers. However, accurate measurement of some non-conservative and low-level analytes such as NO 3 (-) ,NH 4 (+) , total P, and aluminiun in the lakes probably requires more rigorous attention to sampling protocols and holding times. A two-stage sampling strategy employing extensive use of conductivity on a large number of lakes and intensive detailed chemical characterization on a smaller number of lakes offers an alternative design for describing large populations of wilderness lakes. The relatively high concentrations of fluoride and sulfate in many of the study lakes reflect the weathering of minerals not usually identified on geologic maps. These natural sources of acid anions violate the assumptions in commonly employed empirical models of acidification.