Literature DB >> 24218293

A common origin for guanidinobutanoate starter units in antifungal natural products.

Hui Hong1, Taicia Fill, Peter F Leadlay.   

Abstract

Keeping it basic: Arginine provides the exotic 4-guanidinobutanoate starter unit for two different types of zwitterionic polyketide (an example for one type is shown in the picture) produced by the same Streptomyces bacterium. The three-step precursor pathway is initiated by a remarkable decarboxylating monooxygenase with high specificity for arginine.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  antibiotics; biosynthesis; guanidine; macrocyclic polyketides; polyene

Mesh：

Substances：

Year:  2013        PMID： 24218293     DOI： 10.1002/anie.201308136

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  14 in total

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