| Literature DB >> 24161124 |
Rajeev Chorghade1, Claudio Battilocchio, Joel M Hawkins, Steven V Ley.
Abstract
A flow chemistry process for the Oppenauer oxidation of benzylic secondary alcohols using partially hydrated zirconium oxide and a simple carbonyl containing oxidant such as acetone, cyclohexanone, and neopentanal is reported. The heterogeneous oxidative system could be applied to a wide range of functionalized alcohol substrates, allowing clean and fast delivery of ketone products within a few minutes between 40 and 100 °C.Entities:
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Year: 2013 PMID： 24161124 DOI： 10.1021/ol4027107
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005