Literature DB >> 24150640

Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex.

Kazuya Arashiba1, Shogo Kuriyama, Kazunari Nakajima, Yoshiaki Nishibayashi.   

Abstract

A dinitrogen-bridged dimolybdenum-tetrachloride complex is prepared and reduced with Super-Hydride (LiBHEt3) to afford the corresponding dimolybdenum-dinitrogen complex together with the formation of molecular dihydrogen. This reaction proceeds via the ligand exchange of the coordinated dihydrogen generated in situ with molecular dinitrogen.

Entities:  

Year:  2013        PMID： 24150640     DOI： 10.1039/c3cc46946h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

Review 1.  Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes.

Authors:  Matthew J Chalkley; Marcus W Drover; Jonas C Peters
Journal:  Chem Rev       Date:  2020-04-30       Impact factor: 60.622

Review 2.  Activation of Dinitrogen by Polynuclear Metal Complexes.

Authors:  Devender Singh; William R Buratto; Juan F Torres; Leslie J Murray
Journal:  Chem Rev       Date:  2020-05-04       Impact factor: 60.622

3.  Unique behaviour of dinitrogen-bridged dimolybdenum complexes bearing pincer ligand towards catalytic formation of ammonia.

Authors:  Hiromasa Tanaka; Kazuya Arashiba; Shogo Kuriyama; Akira Sasada; Kazunari Nakajima; Kazunari Yoshizawa; Yoshiaki Nishibayashi
Journal:  Nat Commun       Date:  2014-04-28       Impact factor: 14.919

4.  Synthesis and characterization of TADDOL-based chiral group six PNP pincer tricarbonyl complexes.

Authors:  Sara R M M de Aguiar; Christian Schröder-Holzhacker; Jan Pecak; Berthold Stöger; Karl Kirchner
Journal:  Monatsh Chem       Date:  2018-10-20       Impact factor: 1.451
  4 in total

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