Literature DB >> 24132934

Unexpected isomerism in cis-2 bis(pyrrolidino)[60]fullerene diastereomers.

Marta Izquierdo1, Maira R Cerón, Núria Alegret, Alejandro J Metta-Magaña, Antonio Rodríguez-Fortea, Josep M Poblet, Luis Echegoyen.   

Abstract

Similar yet different: A one-step regio- and diastereoselective synthesis of three new bis(pyrrolidine)[60]fullerenes, one cis-1 and two unprecedented cis-2 diastereoisomers, is reported. The compounds are easily purified using simple chromatographic techniques, and were fully characterized by spectroscopic techniques and X-ray crystallography. A mechanism for the isomeric conversion observed is proposed.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  azomethine ylides; cycloaddition; fullerenes; isomerization; structure elucidation

Year:  2013        PMID： 24132934     DOI： 10.1002/anie.201306957

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  2 in total

1.  Fullerene Derivatives Strongly Inhibit HIV-1 Replication by Affecting Virus Maturation without Impairing Protease Activity.

Authors:  Zachary S Martinez; Edison Castro; Chang-Soo Seong; Maira R Cerón; Luis Echegoyen; Manuel Llano
Journal:  Antimicrob Agents Chemother       Date:  2016-09-23       Impact factor: 5.191

2.  Self-Assembly-Directed Organization of a Fullerene-Bisporphyrin into Supramolecular Giant Donut Structures for Excited-State Charge Stabilization.

Authors:  Rubén Caballero; Myriam Barrejón; Jesús Cerdá; Juan Aragó; Sairaman Seetharaman; Pilar de la Cruz; Enrique Ortí; Francis D'Souza; Fernando Langa
Journal:  J Am Chem Soc       Date:  2021-07-14       Impact factor: 15.419
  2 in total

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