| Literature DB >> 24116848 |
Kun Zhao1, Lizhi Zhang, Jiajun Wang, Qunxiang Li, Weiwei He, Jun Jie Yin.
Abstract
We demonstrate that BiOCl single-crystalline nanosheets possess surface structure-dependent molecular oxygen activation properties under UV light. The (001) surface of BiOCl prefers to reduce O2 to ·O2(-) through one-electron transfer, while the (010) surface favors the formation of O2(2-) via two-electron transfer, which is cogoverned by the surface atom exposure and the situ generated oxygen vacancy characteristics of the (001) and (010) surfaces under UV light irradiation.Entities:
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Year: 2013 PMID： 24116848 DOI： 10.1021/ja4092903
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419