[(4E)-1-Methyl-2,6-diphenyl-3-(propan-2-yl)piperidin-4-yl-idene]amino 3-methyl-benzoate.

In the title compound, C29H32N2O2, the piperidine ring exists in a chair conformation (the bond-angle sum at the sp (2)-hybridized C atom is 359.79°). The phenyl rings and the methyl group substituted on the heterocyclic ring are in equatorial orientations. In the crystal, pairs of C-H⋯π inter-actions result in the formation of inversion dimers.

Related literature

For the synthesis and the biological activity of piperidinyl-4-one derivatives, see: Parthiban et al. (2009 ▶, 2011 ▶). For the crystal structures of related compounds, see: Park et al. (2012a ▶,b ▶). For ring puckering parameters, see: Cremer & Pople (1975 ▶).

Experimental

Crystal data

C29H32N2O2

M = 440.57

Triclinic,

a = 10.7837 (4) Å

b = 11.7075 (4) Å

c = 12.0586 (4) Å

α = 114.352 (3)°

β = 96.245 (2)°

γ = 109.530 (5)°

V = 1252.07 (10) Å3

Z = 2

Mo Kα radiation

μ = 0.07 mm−1

T = 293 K

0.20 × 0.20 × 0.20 mm

Data collection

Bruker SMART APEXII CCD diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2008 ▶) T min = 0.986, T max = 0.986

18725 measured reflections

5163 independent reflections

3847 reflections with I > 2σ(I)

R int = 0.028

Refinement

R[F 2 > 2σ(F 2)] = 0.047

wR(F 2) = 0.144

S = 1.04

5163 reflections

298 parameters

H-atom parameters constrained

Δρmax = 0.19 e Å−3

Δρmin = −0.20 e Å−3

Data collection: APEX2 (Bruker, 2008 ▶); cell refinement: SAINT (Bruker, 2008 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012 ▶); software used to prepare material for publication: SHELXL97 and PLATON (Spek, 2009 ▶).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S160053681301893X/pv2632sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S160053681301893X/pv2632Isup2.hkl

Click here for additional data file.

Supplementary material file. DOI: 10.1107/S160053681301893X/pv2632Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C29H32N2O2	Z = 2
Mr = 440.57	F(000) = 472
Triclinic, P1	Dx = 1.169 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 10.7837 (4) Å	Cell parameters from 5207 reflections
b = 11.7075 (4) Å	θ = 1.9–26.5°
c = 12.0586 (4) Å	µ = 0.07 mm−1
α = 114.352 (3)°	T = 293 K
β = 96.245 (2)°	Block, colorless
γ = 109.530 (5)°	0.20 × 0.20 × 0.20 mm
V = 1252.07 (10) Å3

Bruker SMART APEXII CCD diffractometer	5163 independent reflections
Radiation source: fine-focus sealed tube	3847 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.028
ω and φ scans	θmax = 26.6°, θmin = 1.9°
Absorption correction: multi-scan (SADABS; Bruker, 2008)	h = −13→13
Tmin = 0.986, Tmax = 0.986	k = −14→14
18725 measured reflections	l = −15→15

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.047	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.144	H-atom parameters constrained
S = 1.04	w = 1/[σ2(Fo2) + (0.0698P)2 + 0.2364P] where P = (Fo2 + 2Fc2)/3
5163 reflections	(Δ/σ)max < 0.001
298 parameters	Δρmax = 0.19 e Å−3
0 restraints	Δρmin = −0.20 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
C1	0.85940 (14)	0.07747 (14)	0.32666 (13)	0.0429 (3)
H1	0.9292	0.0507	0.3537	0.051*
C2	0.86023 (15)	0.20135 (15)	0.44415 (13)	0.0453 (3)
H2	0.7928	0.2279	0.4125	0.054*
C3	0.99781 (15)	0.31978 (15)	0.48597 (14)	0.0467 (3)
C4	1.02338 (17)	0.35945 (15)	0.38514 (14)	0.0506 (4)
H4A	1.1116	0.4378	0.4169	0.061*
H4B	0.9527	0.3856	0.3610	0.061*
C5	1.02226 (15)	0.23655 (15)	0.26978 (14)	0.0441 (3)
H5	1.0983	0.2159	0.2947	0.053*
C6	0.72125 (15)	−0.04589 (15)	0.27061 (14)	0.0457 (3)
C7	0.71016 (18)	−0.17315 (17)	0.25442 (17)	0.0593 (4)
H7	0.7883	−0.1828	0.2817	0.071*
C8	0.5842 (2)	−0.28672 (18)	0.19804 (19)	0.0709 (5)
H8	0.5786	−0.3721	0.1865	0.085*
C9	0.4681 (2)	−0.27374 (19)	0.15942 (19)	0.0715 (5)
H9	0.3836	−0.3499	0.1219	0.086*
C10	0.47680 (18)	−0.1480 (2)	0.17625 (18)	0.0676 (5)
H10	0.3977	−0.1386	0.1513	0.081*
C11	0.60263 (16)	−0.03497 (17)	0.23022 (16)	0.0555 (4)
H11	0.6076	0.0495	0.2395	0.067*
C12	0.81213 (17)	0.16674 (17)	0.54654 (15)	0.0562 (4)
H12	0.7193	0.0924	0.5043	0.067*
C13	0.7980 (2)	0.2888 (2)	0.64964 (19)	0.0817 (6)
H13A	0.7437	0.3201	0.6108	0.123*
H13B	0.8874	0.3626	0.6981	0.123*
H13C	0.7540	0.2606	0.7048	0.123*
C14	0.8961 (2)	0.1127 (2)	0.60377 (19)	0.0763 (6)
H14A	0.9018	0.0352	0.5370	0.114*
H14B	0.8528	0.0845	0.6592	0.114*
H14C	0.9868	0.1843	0.6513	0.114*
C15	1.29265 (17)	0.54898 (17)	0.72791 (15)	0.0541 (4)
C16	1.41632 (16)	0.65991 (17)	0.73437 (15)	0.0533 (4)
C17	1.49678 (19)	0.7698 (2)	0.85301 (18)	0.0671 (5)
H17	1.4752	0.7713	0.9261	0.081*
C18	1.6094 (2)	0.8772 (2)	0.8616 (2)	0.0790 (6)
H18	1.6626	0.9521	0.9408	0.095*
C19	1.64325 (19)	0.8744 (2)	0.7553 (2)	0.0780 (6)
H19	1.7197	0.9475	0.7632	0.094*
C20	1.56626 (19)	0.7648 (2)	0.6353 (2)	0.0734 (5)
C21	1.45135 (18)	0.65867 (19)	0.62697 (18)	0.0629 (4)
H21	1.3967	0.5852	0.5474	0.075*
C22	1.6026 (3)	0.7604 (3)	0.5167 (3)	0.1156 (9)
H22A	1.6847	0.8408	0.5396	0.173*
H22B	1.5287	0.7586	0.4629	0.173*
H22C	1.6176	0.6790	0.4722	0.173*
C23	1.04536 (16)	0.27730 (15)	0.16717 (14)	0.0480 (4)
C24	1.17432 (18)	0.31908 (16)	0.15031 (17)	0.0592 (4)
H24	1.2461	0.3181	0.1996	0.071*
C25	1.1978 (3)	0.36252 (19)	0.0605 (2)	0.0777 (6)
H25	1.2851	0.3895	0.0496	0.093*
C26	1.0947 (3)	0.3661 (2)	−0.0117 (2)	0.0870 (7)
H26	1.1111	0.3957	−0.0715	0.104*
C27	0.9668 (3)	0.3257 (2)	0.0046 (2)	0.0851 (6)
H27	0.8959	0.3280	−0.0446	0.102*
C28	0.9410 (2)	0.28125 (19)	0.09366 (17)	0.0653 (5)
H28	0.8533	0.2541	0.1037	0.078*
C29	0.90196 (18)	−0.00294 (16)	0.12275 (16)	0.0566 (4)
H29A	0.8183	−0.0841	0.0931	0.085*
H29B	0.9777	−0.0182	0.1534	0.085*
H29C	0.9159	0.0168	0.0541	0.085*
N1	0.89281 (12)	0.11408 (12)	0.22587 (11)	0.0422 (3)
N2	1.08029 (13)	0.36687 (14)	0.59413 (12)	0.0536 (3)
O1	1.20675 (11)	0.47558 (12)	0.60903 (10)	0.0601 (3)
O2	1.26989 (15)	0.52897 (16)	0.81397 (12)	0.0881 (5)

	U11	U22	U33	U12	U13	U23
C1	0.0428 (8)	0.0407 (8)	0.0444 (8)	0.0152 (6)	0.0146 (6)	0.0211 (6)
C2	0.0459 (8)	0.0444 (8)	0.0426 (8)	0.0152 (6)	0.0162 (6)	0.0203 (7)
C3	0.0517 (9)	0.0385 (8)	0.0429 (8)	0.0140 (7)	0.0173 (7)	0.0163 (6)
C4	0.0594 (9)	0.0396 (8)	0.0441 (8)	0.0118 (7)	0.0155 (7)	0.0194 (7)
C5	0.0428 (8)	0.0427 (8)	0.0460 (8)	0.0145 (6)	0.0150 (6)	0.0227 (7)
C6	0.0480 (8)	0.0413 (8)	0.0422 (8)	0.0128 (6)	0.0169 (6)	0.0189 (6)
C7	0.0619 (10)	0.0486 (9)	0.0650 (10)	0.0182 (8)	0.0192 (8)	0.0288 (8)
C8	0.0805 (13)	0.0423 (9)	0.0783 (12)	0.0124 (9)	0.0245 (10)	0.0287 (9)
C9	0.0611 (11)	0.0523 (10)	0.0703 (12)	−0.0010 (8)	0.0195 (9)	0.0215 (9)
C10	0.0495 (10)	0.0627 (11)	0.0708 (11)	0.0123 (8)	0.0141 (8)	0.0241 (9)
C11	0.0523 (9)	0.0457 (9)	0.0584 (9)	0.0144 (7)	0.0149 (7)	0.0212 (8)
C12	0.0529 (9)	0.0560 (9)	0.0473 (8)	0.0091 (7)	0.0193 (7)	0.0235 (8)
C13	0.0864 (14)	0.0854 (14)	0.0633 (12)	0.0285 (12)	0.0426 (11)	0.0278 (11)
C14	0.0871 (14)	0.0762 (13)	0.0683 (12)	0.0196 (11)	0.0222 (10)	0.0485 (11)
C15	0.0545 (9)	0.0547 (9)	0.0462 (8)	0.0158 (8)	0.0118 (7)	0.0243 (8)
C16	0.0471 (9)	0.0518 (9)	0.0548 (9)	0.0148 (7)	0.0074 (7)	0.0264 (8)
C17	0.0614 (11)	0.0642 (11)	0.0579 (10)	0.0168 (9)	0.0018 (8)	0.0247 (9)
C18	0.0592 (12)	0.0597 (12)	0.0859 (14)	0.0090 (9)	−0.0089 (10)	0.0263 (11)
C19	0.0489 (10)	0.0653 (12)	0.1112 (18)	0.0103 (9)	0.0090 (11)	0.0490 (13)
C20	0.0564 (11)	0.0755 (13)	0.0951 (15)	0.0183 (10)	0.0231 (10)	0.0537 (12)
C21	0.0554 (10)	0.0626 (11)	0.0613 (10)	0.0130 (8)	0.0128 (8)	0.0318 (9)
C22	0.1013 (19)	0.129 (2)	0.124 (2)	0.0219 (16)	0.0543 (16)	0.082 (2)
C23	0.0588 (9)	0.0370 (7)	0.0433 (8)	0.0151 (7)	0.0197 (7)	0.0176 (6)
C24	0.0669 (11)	0.0436 (9)	0.0646 (10)	0.0175 (8)	0.0323 (8)	0.0250 (8)
C25	0.1038 (16)	0.0482 (10)	0.0805 (13)	0.0213 (10)	0.0577 (13)	0.0311 (10)
C26	0.146 (2)	0.0545 (11)	0.0625 (12)	0.0292 (13)	0.0480 (14)	0.0356 (10)
C27	0.1183 (19)	0.0780 (14)	0.0636 (12)	0.0364 (13)	0.0173 (12)	0.0436 (11)
C28	0.0720 (12)	0.0676 (11)	0.0576 (10)	0.0244 (9)	0.0169 (9)	0.0355 (9)
C29	0.0635 (10)	0.0456 (9)	0.0530 (9)	0.0194 (8)	0.0279 (8)	0.0170 (7)
N1	0.0444 (7)	0.0371 (6)	0.0409 (6)	0.0132 (5)	0.0170 (5)	0.0168 (5)
N2	0.0506 (8)	0.0492 (7)	0.0468 (7)	0.0062 (6)	0.0148 (6)	0.0218 (6)
O1	0.0528 (6)	0.0585 (7)	0.0453 (6)	0.0001 (5)	0.0095 (5)	0.0236 (5)
O2	0.0826 (9)	0.0981 (11)	0.0548 (8)	0.0003 (8)	0.0104 (7)	0.0431 (8)

C1—N1	1.4874 (17)	C14—H14C	0.9600
C1—C6	1.516 (2)	C15—O2	1.1872 (19)
C1—C2	1.551 (2)	C15—O1	1.3470 (19)
C1—H1	0.9800	C15—C16	1.486 (2)
C2—C3	1.504 (2)	C16—C21	1.384 (2)
C2—C12	1.5391 (19)	C16—C17	1.386 (2)
C2—H2	0.9800	C17—C18	1.383 (3)
C3—N2	1.274 (2)	C17—H17	0.9300
C3—C4	1.491 (2)	C18—C19	1.361 (3)
C4—C5	1.530 (2)	C18—H18	0.9300
C4—H4A	0.9700	C19—C20	1.387 (3)
C4—H4B	0.9700	C19—H19	0.9300
C5—N1	1.4696 (18)	C20—C21	1.389 (2)
C5—C23	1.5150 (19)	C20—C22	1.509 (3)
C5—H5	0.9800	C21—H21	0.9300
C6—C7	1.381 (2)	C22—H22A	0.9600
C6—C11	1.384 (2)	C22—H22B	0.9600
C7—C8	1.386 (2)	C22—H22C	0.9600
C7—H7	0.9300	C23—C24	1.380 (2)
C8—C9	1.365 (3)	C23—C28	1.381 (2)
C8—H8	0.9300	C24—C25	1.386 (3)
C9—C10	1.369 (3)	C24—H24	0.9300
C9—H9	0.9300	C25—C26	1.359 (3)
C10—C11	1.383 (2)	C25—H25	0.9300
C10—H10	0.9300	C26—C27	1.366 (3)
C11—H11	0.9300	C26—H26	0.9300
C12—C14	1.517 (3)	C27—C28	1.389 (3)
C12—C13	1.528 (3)	C27—H27	0.9300
C12—H12	0.9800	C28—H28	0.9300
C13—H13A	0.9600	C29—N1	1.4646 (19)
C13—H13B	0.9600	C29—H29A	0.9600
C13—H13C	0.9600	C29—H29B	0.9600
C14—H14A	0.9600	C29—H29C	0.9600
C14—H14B	0.9600	N2—O1	1.4524 (16)
N1—C1—C6	108.67 (11)	C12—C14—H14C	109.5
N1—C1—C2	111.65 (11)	H14A—C14—H14C	109.5
C6—C1—C2	111.47 (11)	H14B—C14—H14C	109.5
N1—C1—H1	108.3	O2—C15—O1	124.53 (15)
C6—C1—H1	108.3	O2—C15—C16	125.98 (15)
C2—C1—H1	108.3	O1—C15—C16	109.46 (13)
C3—C2—C12	117.24 (12)	C21—C16—C17	119.46 (16)
C3—C2—C1	106.81 (11)	C21—C16—C15	122.52 (15)
C12—C2—C1	114.42 (12)	C17—C16—C15	118.00 (15)
C3—C2—H2	105.8	C18—C17—C16	119.28 (19)
C12—C2—H2	105.8	C18—C17—H17	120.4
C1—C2—H2	105.8	C16—C17—H17	120.4
N2—C3—C4	127.95 (14)	C19—C18—C17	120.68 (19)
N2—C3—C2	119.25 (13)	C19—C18—H18	119.7
C4—C3—C2	112.59 (12)	C17—C18—H18	119.7
C3—C4—C5	108.92 (12)	C18—C19—C20	121.45 (18)
C3—C4—H4A	109.9	C18—C19—H19	119.3
C5—C4—H4A	109.9	C20—C19—H19	119.3
C3—C4—H4B	109.9	C19—C20—C21	117.63 (19)
C5—C4—H4B	109.9	C19—C20—C22	122.0 (2)
H4A—C4—H4B	108.3	C21—C20—C22	120.4 (2)
N1—C5—C23	112.04 (12)	C16—C21—C20	121.47 (18)
N1—C5—C4	110.59 (11)	C16—C21—H21	119.3
C23—C5—C4	108.34 (11)	C20—C21—H21	119.3
N1—C5—H5	108.6	C20—C22—H22A	109.5
C23—C5—H5	108.6	C20—C22—H22B	109.5
C4—C5—H5	108.6	H22A—C22—H22B	109.5
C7—C6—C11	117.98 (14)	C20—C22—H22C	109.5
C7—C6—C1	121.36 (14)	H22A—C22—H22C	109.5
C11—C6—C1	120.62 (13)	H22B—C22—H22C	109.5
C6—C7—C8	120.91 (17)	C24—C23—C28	118.47 (15)
C6—C7—H7	119.5	C24—C23—C5	120.19 (15)
C8—C7—H7	119.5	C28—C23—C5	121.24 (14)
C9—C8—C7	120.25 (17)	C23—C24—C25	120.61 (19)
C9—C8—H8	119.9	C23—C24—H24	119.7
C7—C8—H8	119.9	C25—C24—H24	119.7
C8—C9—C10	119.67 (17)	C26—C25—C24	120.70 (19)
C8—C9—H9	120.2	C26—C25—H25	119.6
C10—C9—H9	120.2	C24—C25—H25	119.6
C9—C10—C11	120.31 (18)	C25—C26—C27	119.22 (18)
C9—C10—H10	119.8	C25—C26—H26	120.4
C11—C10—H10	119.8	C27—C26—H26	120.4
C10—C11—C6	120.85 (16)	C26—C27—C28	120.9 (2)
C10—C11—H11	119.6	C26—C27—H27	119.5
C6—C11—H11	119.6	C28—C27—H27	119.5
C14—C12—C13	111.31 (16)	C23—C28—C27	120.04 (19)
C14—C12—C2	115.51 (14)	C23—C28—H28	120.0
C13—C12—C2	110.75 (14)	C27—C28—H28	120.0
C14—C12—H12	106.2	N1—C29—H29A	109.5
C13—C12—H12	106.2	N1—C29—H29B	109.5
C2—C12—H12	106.2	H29A—C29—H29B	109.5
C12—C13—H13A	109.5	N1—C29—H29C	109.5
C12—C13—H13B	109.5	H29A—C29—H29C	109.5
H13A—C13—H13B	109.5	H29B—C29—H29C	109.5
C12—C13—H13C	109.5	C29—N1—C5	108.29 (11)
H13A—C13—H13C	109.5	C29—N1—C1	108.89 (11)
H13B—C13—H13C	109.5	C5—N1—C1	114.03 (11)
C12—C14—H14A	109.5	C3—N2—O1	108.37 (11)
C12—C14—H14B	109.5	C15—O1—N2	113.56 (11)
H14A—C14—H14B	109.5
N1—C1—C2—C3	−54.46 (15)	C16—C17—C18—C19	−1.4 (3)
C6—C1—C2—C3	−176.20 (12)	C17—C18—C19—C20	0.3 (3)
N1—C1—C2—C12	174.07 (12)	C18—C19—C20—C21	1.2 (3)
C6—C1—C2—C12	52.32 (16)	C18—C19—C20—C22	180.0 (2)
C12—C2—C3—N2	14.7 (2)	C17—C16—C21—C20	0.5 (3)
C1—C2—C3—N2	−115.22 (15)	C15—C16—C21—C20	178.90 (16)
C12—C2—C3—C4	−170.18 (13)	C19—C20—C21—C16	−1.6 (3)
C1—C2—C3—C4	59.93 (15)	C22—C20—C21—C16	179.6 (2)
N2—C3—C4—C5	113.23 (18)	N1—C5—C23—C24	−138.77 (14)
C2—C3—C4—C5	−61.40 (16)	C4—C5—C23—C24	98.96 (16)
C3—C4—C5—N1	55.67 (16)	N1—C5—C23—C28	44.96 (19)
C3—C4—C5—C23	178.82 (12)	C4—C5—C23—C28	−77.31 (18)
N1—C1—C6—C7	112.12 (15)	C28—C23—C24—C25	−0.7 (2)
C2—C1—C6—C7	−124.42 (15)	C5—C23—C24—C25	−177.07 (14)
N1—C1—C6—C11	−65.75 (16)	C23—C24—C25—C26	0.7 (3)
C2—C1—C6—C11	57.72 (17)	C24—C25—C26—C27	−0.3 (3)
C11—C6—C7—C8	0.7 (2)	C25—C26—C27—C28	0.0 (3)
C1—C6—C7—C8	−177.18 (15)	C24—C23—C28—C27	0.4 (3)
C6—C7—C8—C9	−1.1 (3)	C5—C23—C28—C27	176.73 (16)
C7—C8—C9—C10	0.2 (3)	C26—C27—C28—C23	0.0 (3)
C8—C9—C10—C11	1.0 (3)	C23—C5—N1—C29	63.82 (15)
C9—C10—C11—C6	−1.4 (3)	C4—C5—N1—C29	−175.21 (12)
C7—C6—C11—C10	0.5 (2)	C23—C5—N1—C1	−174.80 (11)
C1—C6—C11—C10	178.44 (15)	C4—C5—N1—C1	−53.82 (15)
C3—C2—C12—C14	−66.36 (19)	C6—C1—N1—C29	−61.46 (14)
C1—C2—C12—C14	59.87 (19)	C2—C1—N1—C29	175.18 (12)
C3—C2—C12—C13	61.33 (19)	C6—C1—N1—C5	177.49 (11)
C1—C2—C12—C13	−172.45 (14)	C2—C1—N1—C5	54.13 (15)
O2—C15—C16—C21	164.88 (19)	C4—C3—N2—O1	3.2 (2)
O1—C15—C16—C21	−16.9 (2)	C2—C3—N2—O1	177.53 (12)
O2—C15—C16—C17	−16.7 (3)	O2—C15—O1—N2	0.0 (2)
O1—C15—C16—C17	161.50 (15)	C16—C15—O1—N2	−178.20 (12)
C21—C16—C17—C18	1.0 (3)	C3—N2—O1—C15	169.28 (14)
C15—C16—C17—C18	−177.46 (16)

D—H···A	D—H	H···A	D···A	D—H···A
C11—H11···Cg1i	0.93	2.95	3.778 (2)	149

Table 1

Hydrogen-bond geometry (Å, °)

Cg1 is the centroid of the C16–C21 ring.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C11—H11⋯Cg1i	0.93	2.95	3.778 (2)	149

Symmetry code: (i) .