Literature DB >> 24105400

Structure & bonding of the gold-subhalide cluster I-Au144Cl60[z].

Alfredo Tlahuice-Flores1, David M Black, Stephan B H Bach, Miguel Jose-Yacamán, Robert L Whetten.   

Abstract

The structure and bonding of the gold-subhalide compounds Au144Cl60([z]) are related to those of the ubiquitous thiolated gold clusters, or Faradaurates, by iso-electronic substitution of thiolate by chloride. Exact I-symmetry holds for the [z] = [2+,4+] charge-states, in accordance with new electrospray mass spectrometry measurements and the predicted electron shell filling. The high symmetry facilitates analysis of the global structure as well as the bonding network, with some striking results.

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Year:  2013        PMID: 24105400      PMCID: PMC3867603          DOI: 10.1039/c3cp53902d

Source DB:  PubMed          Journal:  Phys Chem Chem Phys        ISSN: 1463-9076            Impact factor:   3.676


  18 in total

1.  Faradaurate nanomolecules: a superstable plasmonic 76.3 kDa cluster.

Authors:  Amala Dass
Journal:  J Am Chem Soc       Date:  2011-11-11       Impact factor: 15.419

2.  The halogen analogs of thiolated gold nanoclusters.

Authors:  De-en Jiang; Michael Walter
Journal:  Nanoscale       Date:  2012-04-27       Impact factor: 7.790

3.  Ligand symmetry-equivalence on thiolate protected gold nanoclusters determined by NMR spectroscopy.

Authors:  O Andrea Wong; Christine L Heinecke; Ashli R Simone; Robert L Whetten; Christopher J Ackerson
Journal:  Nanoscale       Date:  2012-04-30       Impact factor: 7.790

4.  Size-dependent transition to high-symmetry chiral structures in AgCu, AgCo, AgNi, and AuNi nanoalloys.

Authors:  Davide Bochicchio; Riccardo Ferrando
Journal:  Nano Lett       Date:  2010-10-13       Impact factor: 11.189

5.  Electrospray ionization mass spectrometry of intrinsically cationized nanoparticles, [Au(144/146)(SC(11)H(22)N(CH(2)CH(3))(3)(+))(x)(S(CH(2))(5)CH(3))(y)](x+).

Authors:  Christina A Fields-Zinna; Rajesh Sardar; Christopher A Beasley; Royce W Murray
Journal:  J Am Chem Soc       Date:  2009-11-11       Impact factor: 15.419

6.  (AuAg)144(SR)60 alloy nanomolecules.

Authors:  Chanaka Kumara; Amala Dass
Journal:  Nanoscale       Date:  2011-07-13       Impact factor: 7.790

7.  Controlling nanoparticles with atomic precision: the case of Au144(SCH2CH2Ph)60.

Authors:  Huifeng Qian; Rongchao Jin
Journal:  Nano Lett       Date:  2009-12       Impact factor: 11.189

8.  STEM Electron Diffraction and High Resolution Images Used in the Determination of the Crystal Structure of Au144(SR)60 Cluster.

Authors:  Daniel Bahena; Nabraj Bhattarai; Ulises Santiago; Alfredo Tlahuice; Arturo Ponce; Stephan B H Bach; Bokwon Yoon; Robert L Whetten; Uzi Landman; Miguel Jose-Yacaman
Journal:  J Phys Chem Lett       Date:  2013-03-07       Impact factor: 6.475

9.  Ubiquitous 8 and 29 kDa gold:alkanethiolate cluster compounds: mass-spectrometric determination of molecular formulas and structural implications.

Authors:  Nirmalya K Chaki; Yuichi Negishi; Hironori Tsunoyama; Yukatsu Shichibu; Tatsuya Tsukuda
Journal:  J Am Chem Soc       Date:  2008-06-12       Impact factor: 15.419

10.  Structure of a thiol monolayer-protected gold nanoparticle at 1.1 A resolution.

Authors:  Pablo D Jadzinsky; Guillermo Calero; Christopher J Ackerson; David A Bushnell; Roger D Kornberg
Journal:  Science       Date:  2007-10-19       Impact factor: 47.728

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  11 in total

1.  Collision-induced dissociation of monolayer protected clusters Au144 and Au130 in an electrospray time-of-flight mass spectrometer.

Authors:  David M Black; Nabraj Bhattarai; Robert L Whetten; Stephan B H Bach
Journal:  J Phys Chem A       Date:  2014-10-31       Impact factor: 2.781

2.  Interaction between functionalized gold nanoparticles in physiological saline.

Authors:  Shada A Alsharif; Liao Y Chen; Alfredo Tlahuice-Flores; Robert L Whetten; Miguel Jose Yacaman
Journal:  Phys Chem Chem Phys       Date:  2014-03-07       Impact factor: 3.676

3.  Ligand-modulated interactions between charged monolayer-protected Au144(SR)60 gold nanoparticles in physiological saline.

Authors:  Oscar D Villarreal; Liao Y Chen; Robert L Whetten; Miguel J Yacaman
Journal:  Phys Chem Chem Phys       Date:  2015-02-07       Impact factor: 3.676

4.  Molecular dynamics simulations on the effect of size and shape on the interactions between negative Au18(SR)14, Au102(SR)44 and Au144(SR)60 nanoparticles in physiological saline.

Authors:  Oscar D Villareal; Roberto A Rodriguez; Lili Yu; Thierry O Wambo
Journal:  Colloids Surf A Physicochem Eng Asp       Date:  2016-08-20       Impact factor: 4.539

5.  Aspheric Solute Ions Modulate Gold Nanoparticle Interactions in an Aqueous Solution: An Optimal Way To Reversibly Concentrate Functionalized Nanoparticles.

Authors:  Oscar D Villarreal; Liao Y Chen; Robert L Whetten; Borries Demeler
Journal:  J Phys Chem B       Date:  2015-12-03       Impact factor: 2.991

6.  Structure-conserving spontaneous transformations between nanoparticles.

Authors:  K R Krishnadas; Ananya Baksi; Atanu Ghosh; Ganapati Natarajan; Thalappil Pradeep
Journal:  Nat Commun       Date:  2016-11-10       Impact factor: 14.919

7.  Determining the composition of gold nanoparticles: a compilation of shapes, sizes, and calculations using geometric considerations.

Authors:  Taizo Mori; Torsten Hegmann
Journal:  J Nanopart Res       Date:  2016-10-03       Impact factor: 2.253

8.  Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates.

Authors:  Seiji Yamazoe; Shinjiro Takano; Wataru Kurashige; Toshihiko Yokoyama; Kiyofumi Nitta; Yuichi Negishi; Tatsuya Tsukuda
Journal:  Nat Commun       Date:  2016-01-18       Impact factor: 14.919

9.  Polymorphism in magic-sized Au144(SR)60 clusters.

Authors:  Kirsten M Ø Jensen; Pavol Juhas; Marcus A Tofanelli; Christine L Heinecke; Gavin Vaughan; Christopher J Ackerson; Simon J L Billinge
Journal:  Nat Commun       Date:  2016-06-14       Impact factor: 14.919

10.  Unraveling the long-pursued Au144 structure by x-ray crystallography.

Authors:  Nan Yan; Nan Xia; Lingwen Liao; Min Zhu; Fengming Jin; Rongchao Jin; Zhikun Wu
Journal:  Sci Adv       Date:  2018-10-12       Impact factor: 14.136

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