Literature DB >> 24099324

Iron-catalyzed aerobic oxidation of allylic alcohols: the issue of C═C bond isomerization.

Jinxian Liu1, Shengming Ma.   

Abstract

An aerobic oxidation of allylic alcohols using Fe(NO3)3·9H2O/TEMPO/NaCl as catalysts under atmospheric pressure of oxygen at room temperature was developed. This eco-friendly and mild protocol provides a convenient pathway to the synthesis of stereodefined α,β-unsaturated enals or enones with the retention of the C-C double-bond configuration.

Entities:  

Year:  2013        PMID： 24099324     DOI： 10.1021/ol402434x

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Oxidizable Ketones: Persistent Radical Cations from the Single-Electron Oxidation of 2,3-Diaminocyclopropenones.

Authors:  Zack M Strater; Michael Rauch; Steffen Jockusch; Tristan H Lambert
Journal:  Angew Chem Int Ed Engl       Date:  2019-05-08       Impact factor: 15.336

2.  Copper-Catalyzed Synthesis of N-Aryl and N-Sulfonyl Indoles from 2-Vinylanilines with O2 as Terminal Oxidant and TEMPO as Co-Catalyst.

Authors:  Timothy W Liwosz; Sherry R Chemler
Journal:  Synlett       Date:  2014       Impact factor: 2.454

3.  Aerobic alcohol oxidation and oxygen atom transfer reactions catalyzed by a nonheme iron(ii)-α-keto acid complex.

Authors:  Debobrata Sheet; Tapan Kanti Paine
Journal:  Chem Sci       Date:  2016-04-25       Impact factor: 9.825

4.  Selective Aerobic Oxidation of Alcohols in Low Melting Mixtures and Water and Use for Telescoped One-Pot Hybrid Reactions.

Authors:  Luciana Cicco; Marianna Roggio; Marcos López-Aguilar; Marina Ramos-Martín; Filippo Maria Perna; Joaquín García-Álvarez; Paola Vitale; Vito Capriati
Journal:  ChemistryOpen       Date:  2022-10       Impact factor: 2.630
  4 in total

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