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Literature DB >> 24064606

Activation of carbon-hydrogen bonds and dihydrogen by 1,2-CH-addition across metal-heteroatom bonds.

Joanna R Webb¹, Samantha A Burgess, Thomas R Cundari, T Brent Gunnoe.

Abstract

The controlled conversion of hydrocarbons to functionalized products requires selective C-H bond cleavage. This perspective provides an overview of 1,2-CH-addition of hydrocarbons across d(0) transition metal imido complexes and compares and contrasts these to examples of analogous reactions that involve later transition metal amide, hydroxide and alkoxide complexes with d(6) and d(8) metals.

Entities: Chemical

Year: 2013 PMID： 24064606 DOI： 10.1039/c3dt52164h

Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390

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Cited

6 in total

Review 1. Engendering reactivity at group 5-heteroatom multiple bonds via π-loading.

Authors: Jade I Fostvedt; Jocelyne Mendoza; Sacy Lopez-Flores; Diego Alcantar; Robert G Bergman; John Arnold
Journal: Chem Sci Date: 2022-06-29 Impact factor: 9.969

2. Reactivity of terminal imido complexes of group 4-6 metals: stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules.

Authors: Kento Kawakita; Yuya Kakiuchi; Hayato Tsurugi; Kazushi Mashima; Bernard F Parker; John Arnold; Ian A Tonks
Journal: Coord Chem Rev Date: 2020-01-14 Impact factor: 22.315

3. Mechanistic and Kinetic Studies of the Direct Alkylation of Benzylic Amines: A Formal C(sp³)-H Activation Proceeds Actually via a C(sp²)-H Activation Pathway.

Authors: Robert Pollice; Navid Dastbaravardeh; Nada Marquise; Marko D Mihovilovic; Michael Schnürch
Journal: ACS Catal Date: 2014-12-08 Impact factor: 13.084

Activation of carbon-hydrogen bonds and dihydrogen by 1,2-CH-addition across metal-heteroatom bonds.

Review 1. Engendering reactivity at group 5-heteroatom multiple bonds via π-loading.

2. Reactivity of terminal imido complexes of group 4-6 metals: stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules.

3. Mechanistic and Kinetic Studies of the Direct Alkylation of Benzylic Amines: A Formal C(sp³)-H Activation Proceeds Actually via a C(sp²)-H Activation Pathway.

4. Computational Study of Methane C-H Activation by Main Group and Mixed Main Group-Transition Metal Complexes.

Review 5. Metathesis by Partner Interchange in σ-Bond Ligands: Expanding Applications of the σ-CAM Mechanism.

Review 6. Applications of density functional theory to iron-containing molecules of bioinorganic interest.

Activation of carbon-hydrogen bonds and dihydrogen by 1,2-CH-addition across metal-heteroatom bonds.

Review 1. Engendering reactivity at group 5-heteroatom multiple bonds via π-loading.

2. Reactivity of terminal imido complexes of group 4-6 metals: stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules.

3. Mechanistic and Kinetic Studies of the Direct Alkylation of Benzylic Amines: A Formal C(sp3)-H Activation Proceeds Actually via a C(sp2)-H Activation Pathway.

4. Computational Study of Methane C-H Activation by Main Group and Mixed Main Group-Transition Metal Complexes.

Review 5. Metathesis by Partner Interchange in σ-Bond Ligands: Expanding Applications of the σ-CAM Mechanism.

Review 6. Applications of density functional theory to iron-containing molecules of bioinorganic interest.

3. Mechanistic and Kinetic Studies of the Direct Alkylation of Benzylic Amines: A Formal C(sp³)-H Activation Proceeds Actually via a C(sp²)-H Activation Pathway.