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Literature DB >> 23946248

Enantiomer-specific oriented attachment: formation of macroscopic homochiral crystal aggregates from a racemic system.

Cristóbal Viedma¹, J Michael McBride, Bart Kahr, Pedro Cintas.

Abstract

Let's get together: Racemic samples of d- and l-enantiomorphous NaBrO3 (or NaClO3) crystals aggregate with nearly complete enantioselection. Centimeter-sized enantiopure megacrystals are often produced, and these can be sorted easily.

Entities: Chemical

Keywords: alignment mechanism; chirality; crystal growth; enantioselection; oriented attachment

Year: 2013 PMID： 23946248 DOI： 10.1002/anie.201303915

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

Keyword Cloud
Cited

8 in total

1. Nanoparticle self-assembly: Enantioselective photoactivation.

Authors: Bart Kahr; Alexander G Shtukenberg
Journal: Nat Mater Date: 2015-01 Impact factor: 43.841

2. Cooperative expression of atomic chirality in inorganic nanostructures.

Authors: Peng-Peng Wang; Shang-Jie Yu; Alexander O Govorov; Min Ouyang
Journal: Nat Commun Date: 2017-02-02 Impact factor: 14.919

3. Cation-mediated optical resolution and anticancer activity of chiral polyoxometalates built from entirely achiral building blocks.

Authors: Zhi-Ming Zhang; Xiaopin Duan; Shuang Yao; Zhishu Wang; Zekai Lin; Yang-Guang Li; La-Sheng Long; En-Bo Wang; Wenbin Lin
Journal: Chem Sci Date: 2016-03-09 Impact factor: 9.825

4. Enantiomer-selective magnetization of conglomerates for quantitative chiral separation.

Authors: Xichong Ye; Jiaxi Cui; Bowen Li; Na Li; Rong Wang; Zijia Yan; Junyan Tan; Jie Zhang; Xinhua Wan
Journal: Nat Commun Date: 2019-04-29 Impact factor: 14.919

5. Homochirality in biomineral suprastructures induced by assembly of single-enantiomer amino acids from a nonracemic mixture.

Authors: Wenge Jiang; Dimitra Athanasiadou; Shaodong Zhang; Raffaella Demichelis; Katarzyna B Koziara; Paolo Raiteri; Valentin Nelea; Wenbo Mi; Jun-An Ma; Julian D Gale; Marc D McKee
Journal: Nat Commun Date: 2019-05-24 Impact factor: 14.919

Enantiomer-specific oriented attachment: formation of macroscopic homochiral crystal aggregates from a racemic system.

1. Nanoparticle self-assembly: Enantioselective photoactivation.

2. Cooperative expression of atomic chirality in inorganic nanostructures.

3. Cation-mediated optical resolution and anticancer activity of chiral polyoxometalates built from entirely achiral building blocks.

4. Enantiomer-selective magnetization of conglomerates for quantitative chiral separation.

5. Homochirality in biomineral suprastructures induced by assembly of single-enantiomer amino acids from a nonracemic mixture.

6. Tuning organic crystal chirality by the molar masses of tailored polymeric additives.

7. Oriented attachment growth of monocrystalline cuprous oxide nanowires in pure water.

8. A molecular propeller effect for chiral separation and analysis.