Literature DB >> 23944937

Cu-NHC-TEMPO catalyzed aerobic oxidation of primary alcohols to aldehydes.

Xiaolong Liu1, Qinqin Xia, Yuejiao Zhang, Congyan Chen, Wanzhi Chen.   

Abstract

Imidazolium salts bearing TEMPO groups react with commercially available copper powder affording Cu-NHC complexes. The in situ generated Cu-NHC-TEMPO complexes are quite efficient catalysts for aerobic oxidation of primary alcohols into aldehydes. The catalyst is easily available, and various primary alcohols were selectively converted to aldehydes in excellent yields.

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Year:  2013        PMID: 23944937     DOI: 10.1021/jo401252d

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  4 in total

Review 1.  Practical aerobic oxidations of alcohols and amines with homogeneous copper/TEMPO and related catalyst systems.

Authors:  Bradford L Ryland; Shannon S Stahl
Journal:  Angew Chem Int Ed Engl       Date:  2014-07-07       Impact factor: 15.336

2.  DNA-Scaffolded Synergistic Catalysis.

Authors:  Edward B Pimentel; Trenton M Peters-Clarke; Joshua J Coon; Jeffrey D Martell
Journal:  J Am Chem Soc       Date:  2021-12-13       Impact factor: 16.383

3.  A resorcin[4]arene hexameric capsule as a supramolecular catalyst in elimination and isomerization reactions.

Authors:  Tommaso Lorenzetto; Fabrizio Fabris; Alessandro Scarso
Journal:  Beilstein J Org Chem       Date:  2022-03-28       Impact factor: 2.883

4.  An Unexpected Controlled New Oxidant: SO4(·-).

Authors:  Cui-Bing Bai; Nai-Xing Wang; Xing-Wang Lan; Yan-Jing Wang; Yalan Xing; Jia-Long Wen; Xue-Wang Gao; Wei Zhang
Journal:  Sci Rep       Date:  2016-02-01       Impact factor: 4.379

  4 in total

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