Literature DB >> 23772443

A change in the oxidation state of iron: scandium is not innocent.

Marcel Swart1.   

Abstract

Through extensive molecular modelling of Fe(III/IV)-oxo and Fe(III)-hydroxo complexes it is shown here unambiguously that the assignment of the iron oxidation state of a Sc(3+)-capped iron-oxygen species should be revised. Iron in this Lewis-acid capped metal-bound oxygen system is Fe(III), coinciding with water as a secondary axial ligand to scandium.

Entities:  

Year:  2013        PMID： 23772443     DOI： 10.1039/c3cc42200c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  10 in total

1.  Effects of Lewis Acidic Metal Ions (M) on Oxygen-Atom Transfer Reactivity of Heterometallic Mn3MO4 Cubane and Fe3MO(OH) and Mn3MO(OH) Clusters.

Authors:  Davide Lionetti; Sandy Suseno; Emily Y Tsui; Luo Lu; Troy A Stich; Kurtis M Carsch; Robert J Nielsen; William A Goddard; R David Britt; Theodor Agapie
Journal:  Inorg Chem       Date:  2019-02-07       Impact factor: 5.165

Review 2.  Mono- and binuclear non-heme iron chemistry from a theoretical perspective.

Authors:  Tibor András Rokob; Jakub Chalupský; Daniel Bím; Prokopis C Andrikopoulos; Martin Srnec; Lubomír Rulíšek
Journal:  J Biol Inorg Chem       Date:  2016-05-26       Impact factor: 3.358

3.  The Two Faces of Tetramethylcyclam in Iron Chemistry: Distinct Fe-O-M Complexes Derived from [FeIV(Oanti/syn)(TMC)]2+ Isomers.

Authors:  Ang Zhou; Jai Prakash; Gregory T Rohde; Johannes E M N Klein; Scott T Kleespies; Apparao Draksharapu; Ruixi Fan; Yisong Guo; Christopher J Cramer; Lawrence Que
Journal:  Inorg Chem       Date:  2016-12-21       Impact factor: 5.165

4.  Spectroscopic identification of an Fe(III) center, not Fe(IV), in the crystalline Sc-O-Fe adduct derived from [Fe(IV)(O)(TMC)]²⁺.

Authors:  Jai Prakash; Gregory T Rohde; Katlyn K Meier; Andrew J Jasniewski; Katherine M Van Heuvelen; Eckard Münck; Lawrence Que
Journal:  J Am Chem Soc       Date:  2015-03-06       Impact factor: 15.419

5.  Reactivity of an FeIV-Oxo Complex with Protons and Oxidants.

Authors:  Ethan A Hill; Andrew C Weitz; Elizabeth Onderko; Adrian Romero-Rivera; Yisong Guo; Marcel Swart; Emile L Bominaar; Michael T Green; Michael P Hendrich; David C Lacy; A S Borovik
Journal:  J Am Chem Soc       Date:  2016-09-30       Impact factor: 15.419

6.  Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with FeV═O and FeIV═O Units.

Authors:  Santanu Pattanayak; Andrew J Jasniewski; Atanu Rana; Apparao Draksharapu; Kundan K Singh; Andrew Weitz; Michael Hendrich; Lawrence Que; Abhishek Dey; Sayam Sen Gupta
Journal:  Inorg Chem       Date:  2017-05-08       Impact factor: 5.165

7.  Effects of Noncovalent Interactions on High-Spin Fe(IV)-Oxido Complexes.

Authors:  Victoria F Oswald; Justin L Lee; Saborni Biswas; Andrew C Weitz; Kaustuv Mittra; Ruixi Fan; Jikun Li; Jiyong Zhao; Michael Y Hu; Esen E Alp; Emile L Bominaar; Yisong Guo; Michael T Green; Michael P Hendrich; A S Borovik
Journal:  J Am Chem Soc       Date:  2020-06-24       Impact factor: 15.419

8.  Characterization of a heterobimetallic nonheme Fe(III)-O-Cr(III) species formed by O2 activation.

Authors:  Ang Zhou; Scott T Kleespies; Katherine M Van Heuvelen; Lawrence Que
Journal:  Chem Commun (Camb)       Date:  2015-08-12       Impact factor: 6.222

9.  Rapid Iron(III)-Fluoride-Mediated Hydrogen Atom Transfer.

Authors:  Chakadola Panda; Lorna M Doyle; Robert Gericke; Aidan R McDonald
Journal:  Angew Chem Int Ed Engl       Date:  2021-11-05       Impact factor: 16.823

10.  Lewis versus Brønsted Acid Activation of a Mn(IV) Catalyst for Alkene Oxidation.

Authors:  Jorn D Steen; Stepan Stepanovic; Mahsa Parvizian; Johannes W de Boer; Ronald Hage; Juan Chen; Marcel Swart; Maja Gruden; Wesley R Browne
Journal:  Inorg Chem       Date:  2019-10-18       Impact factor: 5.165
  10 in total

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