| Literature DB >> 23736892 |
Shao-Jie Lou1, Dan-Qian Xu, Ai-Bao Xia, Yi-Feng Wang, Yun-Kui Liu, Xiao-Hua Du, Zhen-Yuan Xu.
Abstract
A novel Pd(OAc)2-NFSI-TFA system was developed for the highly selective ortho-monofluorination directed by diverse aryl-N-heterocyclic directing groups e.g., quinoxaline, pyrazole, benzo[d]oxazole, and pyrazine derivatives. A Pd(II/IV) catalytic cycle was proposed based on the ESI-MS/MS studies.Entities:
Year: 2013 PMID： 23736892 DOI： 10.1039/c3cc42220h
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222