{2,2'-[N,N'-Bis(pyridin-2-ylmeth-yl)propane-1,3-diyldi(nitrilo)]di-acetato}-cobalt(III) hexa-fluoridophosphate aceto-nitrile 0.064-solvate.

In the title compound, [Co(C19H22N4O4)]PF6·0.064CH3CN, commonly known as [Co(bppd)]PF6·0.064CH3CN, where bppd represents the historical ligand name N,N'-bis(2-pyridylmethyl)-1,3-diaminopropane-N,N'-diacetate, the Co(III) atom is coordinated in a distorted octa-hedral geometry with an N4O2 donor atom set. The acetate O atoms, which exhibit monodentate coordination, are oriented in a trans configuration with respect to each other, whereas the pyridyl N atoms are coordinated in a cis configuration. The compound crystallizes with two crystallographically unique cations and two anions per asymmetric unit along with a disordered, partially occupied (occupancy = 0.128) aceto-nitrile solvent mol-ecule. Crystals of the title complex were found to be twinned by pseudomerohedry with a 180° rotation around [10-1] and a refined contribution of 90.5 (3)% of the major twin component.

Related literature

For this and related ligands, see: Lacoste et al. (1965 ▶); Caravan et al. (1997 ▶); Kanamori et al. (2001 ▶); Kissel et al. (2013 ▶). For a structure with a derivative of this ligand, see: Sato et al. (2012 ▶). For a related CoIII-N,N′-bis­(2-pyridyl­meth­yl)-1,2-di­amino­ethane-N,N′-di­acetate complex, [Co(bped)+], see: Caravan et al. (1997 ▶). For literature on possible applications, see: Caravan et al. (1997 ▶); Geraldes (1999 ▶); Jensen (2000 ▶); Heitzmann et al. (2009 ▶); Ogden et al. (2012 ▶); Sato et al. (2012 ▶).

Experimental

Crystal data

[Co(C19H22N4O4)]PF6·0.064C2H3N

M = 576.80

Monoclinic,

a = 21.8891 (7) Å

b = 10.2350 (3) Å

c = 21.9242 (7) Å

β = 112.802 (2)°

V = 4527.9 (2) Å3

Z = 8

Mo Kα radiation

μ = 0.91 mm−1

T = 100 K

0.46 × 0.23 × 0.16 mm

Data collection

Bruker APEXII diffractometer equipped with a CCD detector

Absorption correction: multi-scan (SADABS; Bruker, 2008 ▶) T min = 0.680, T max = 0.871

98080 measured reflections

10379 independent reflections

9851 reflections with I > 2σ(I)

R int = 0.028

Refinement

R[F 2 > 2σ(F 2)] = 0.025

wR(F 2) = 0.074

S = 1.28

10379 reflections

645 parameters

H-atom parameters constrained

Δρmax = 0.64 e Å−3

Δρmin = −0.48 e Å−3

Data collection: APEX2 (Bruker, 2008 ▶); cell refinement: SAINT (Bruker, 2008 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012 ▶); software used to prepare material for publication: enCIFer (Allen et al., 2004 ▶).

Click here for additional data file.

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536813011136/wm2736sup1.cif

Click here for additional data file.

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536813011136/wm2736Isup2.hkl

Click here for additional data file.

Supplementary material file. DOI: 10.1107/S1600536813011136/wm2736Isup3.cdx

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Co(C19H22N4O4)]PF6·0.064C2H3N	F(000) = 2346
Mr = 576.80	Dx = 1.692 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
a = 21.8891 (7) Å	Cell parameters from 9929 reflections
b = 10.2350 (3) Å	θ = 2.2–31.9°
c = 21.9242 (7) Å	µ = 0.91 mm−1
β = 112.802 (2)°	T = 100 K
V = 4527.9 (2) Å3	Cut block, translucent dark red-orange
Z = 8	0.46 × 0.23 × 0.16 mm

Bruker APEXII diffractometer equipped with a CCD detector	10379 independent reflections
Radiation source: fine-focus sealed tube	9851 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.028
Detector resolution: 8.3333 pixels mm-1	θmax = 27.5°, θmin = 1.0°
φ and ω scans	h = −28→28
Absorption correction: multi-scan (SADABS; Bruker, 2008)	k = −13→12
Tmin = 0.680, Tmax = 0.871	l = −28→27
98080 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.025	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.074	H-atom parameters constrained
S = 1.28	w = 1/[σ2(Fo2) + (0.0454P)2] where P = (Fo2 + 2Fc2)/3
10379 reflections	(Δ/σ)max = 0.001
645 parameters	Δρmax = 0.64 e Å−3
0 restraints	Δρmin = −0.48 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Co1	0.680379 (10)	0.290022 (18)	0.624729 (10)	0.00956 (5)
O1	0.63681 (5)	0.32269 (11)	0.53348 (5)	0.0132 (2)
O2	0.53601 (5)	0.35871 (10)	0.45664 (5)	0.0158 (2)
O3	0.72325 (5)	0.26154 (11)	0.71680 (5)	0.0127 (2)
O4	0.78066 (6)	0.36604 (11)	0.81082 (5)	0.0202 (2)
N1	0.63416 (6)	0.12289 (12)	0.60754 (6)	0.0120 (2)
N2	0.60034 (6)	0.34784 (12)	0.63686 (6)	0.0105 (2)
N3	0.76133 (6)	0.23423 (14)	0.61607 (7)	0.0152 (3)
N4	0.72306 (6)	0.46240 (12)	0.63882 (6)	0.0135 (2)
C1	0.63753 (8)	0.02776 (15)	0.56666 (8)	0.0175 (3)
H1A	0.6680	0.0363	0.5456	0.021*
C2	0.59791 (9)	−0.08206 (16)	0.55439 (8)	0.0223 (4)
H2A	0.6012	−0.1482	0.5254	0.027*
C3	0.55346 (8)	−0.09469 (16)	0.58478 (9)	0.0240 (4)
H3A	0.5271	−0.1711	0.5783	0.029*
C4	0.54785 (8)	0.00546 (16)	0.62489 (9)	0.0200 (3)
H4A	0.5169	−0.0004	0.6455	0.024*
C5	0.58810 (7)	0.11385 (14)	0.63437 (7)	0.0129 (3)
C6	0.58279 (7)	0.23440 (15)	0.67041 (7)	0.0128 (3)
H6A	0.6137	0.2296	0.7174	0.015*
H6B	0.5371	0.2443	0.6686	0.015*
C7	0.54826 (7)	0.37022 (15)	0.56912 (7)	0.0132 (3)
H7A	0.5314	0.4607	0.5663	0.016*
H7B	0.5107	0.3100	0.5620	0.016*
C8	0.57420 (7)	0.34900 (13)	0.51470 (7)	0.0119 (3)
C9	0.60885 (7)	0.46390 (14)	0.68086 (7)	0.0138 (3)
H9A	0.6416	0.4416	0.7255	0.017*
H9B	0.5661	0.4814	0.6850	0.017*
C10	0.63131 (8)	0.58850 (15)	0.65802 (8)	0.0184 (3)
H10A	0.6557	0.6421	0.6976	0.022*
H10B	0.5913	0.6383	0.6306	0.022*
C11	0.67509 (8)	0.57374 (15)	0.61848 (8)	0.0161 (3)
H11A	0.6461	0.5627	0.5712	0.019*
H11B	0.7003	0.6558	0.6225	0.019*
C12	0.78860 (8)	0.11362 (17)	0.62926 (8)	0.0201 (3)
H12A	0.7654	0.0452	0.6404	0.024*
C13	0.84984 (9)	0.08817 (19)	0.62679 (10)	0.0279 (4)
H13A	0.8678	0.0024	0.6347	0.033*
C14	0.88440 (10)	0.1886 (2)	0.61265 (10)	0.0307 (4)
H14A	0.9259	0.1722	0.6098	0.037*
C15	0.85800 (9)	0.31391 (19)	0.60268 (9)	0.0245 (4)
H15A	0.8821	0.3851	0.5952	0.029*
C16	0.79558 (8)	0.33316 (17)	0.60381 (8)	0.0178 (3)
C17	0.76100 (8)	0.46245 (16)	0.59474 (8)	0.0177 (3)
H17A	0.7937	0.5346	0.6070	0.021*
H17B	0.7305	0.4741	0.5480	0.021*
C18	0.76896 (7)	0.47169 (15)	0.71010 (7)	0.0154 (3)
H18A	0.7620	0.5562	0.7284	0.019*
H18B	0.8154	0.4689	0.7135	0.019*
C19	0.75738 (7)	0.36034 (14)	0.75052 (8)	0.0137 (3)
Co2	0.127881 (10)	0.206242 (17)	0.666003 (10)	0.00865 (5)
O5	0.21806 (5)	0.23182 (10)	0.72040 (5)	0.0121 (2)
O6	0.30655 (6)	0.12785 (11)	0.79108 (6)	0.0230 (3)
O7	0.03857 (5)	0.17621 (10)	0.61087 (5)	0.0131 (2)
O8	−0.02655 (5)	0.14861 (11)	0.50480 (6)	0.0179 (2)
N5	0.10676 (6)	0.26211 (13)	0.74014 (6)	0.0140 (3)
N6	0.13431 (6)	0.03316 (12)	0.70686 (6)	0.0119 (2)
N7	0.11816 (6)	0.37471 (12)	0.62093 (6)	0.0104 (2)
N8	0.15295 (6)	0.14819 (12)	0.59347 (6)	0.0099 (2)
C20	0.11881 (8)	0.38126 (16)	0.76838 (8)	0.0180 (3)
H20A	0.1335	0.4493	0.7479	0.022*
C21	0.11032 (10)	0.40688 (18)	0.82670 (9)	0.0265 (4)
H21A	0.1180	0.4920	0.8454	0.032*
C22	0.09057 (12)	0.30666 (18)	0.85706 (10)	0.0305 (4)
H22A	0.0847	0.3223	0.8972	0.037*
C23	0.07924 (10)	0.18297 (18)	0.82882 (10)	0.0262 (4)
H23A	0.0658	0.1130	0.8492	0.031*
C24	0.08809 (8)	0.16379 (16)	0.76996 (8)	0.0179 (3)
C25	0.08214 (8)	0.03443 (15)	0.73538 (8)	0.0168 (3)
H25A	0.0893	−0.0384	0.7671	0.020*
H25B	0.0375	0.0250	0.6998	0.020*
C26	0.20196 (8)	0.02161 (15)	0.76059 (7)	0.0153 (3)
H26A	0.2220	−0.0626	0.7559	0.018*
H26B	0.1981	0.0218	0.8041	0.018*
C27	0.24717 (8)	0.13318 (14)	0.75825 (7)	0.0144 (3)
C28	0.11960 (7)	−0.07812 (14)	0.65890 (7)	0.0138 (3)
H28A	0.0746	−0.0659	0.6245	0.017*
H28B	0.1193	−0.1602	0.6827	0.017*
C29	0.16849 (8)	−0.09321 (15)	0.62498 (8)	0.0150 (3)
H29A	0.1460	−0.1422	0.5833	0.018*
H29B	0.2059	−0.1478	0.6538	0.018*
C30	0.19734 (7)	0.03175 (14)	0.60843 (7)	0.0127 (3)
H30A	0.2390	0.0532	0.6462	0.015*
H30B	0.2088	0.0142	0.5697	0.015*
C31	0.07496 (7)	0.47038 (14)	0.61800 (7)	0.0126 (3)
H31A	0.0491	0.4633	0.6440	0.015*
C32	0.06728 (7)	0.57872 (15)	0.57810 (7)	0.0143 (3)
H32A	0.0366	0.6454	0.5769	0.017*
C33	0.10461 (8)	0.58906 (15)	0.54001 (8)	0.0165 (3)
H33A	0.1008	0.6639	0.5132	0.020*
C34	0.14785 (8)	0.48846 (15)	0.54148 (8)	0.0173 (3)
H34A	0.1737	0.4931	0.5154	0.021*
C35	0.15248 (7)	0.38192 (14)	0.58144 (7)	0.0116 (3)
C36	0.19088 (7)	0.26107 (15)	0.58220 (7)	0.0123 (3)
H36A	0.2355	0.2658	0.6180	0.015*
H36B	0.1960	0.2508	0.5395	0.015*
C37	0.08966 (7)	0.12739 (15)	0.53421 (7)	0.0128 (3)
H37A	0.0883	0.0364	0.5185	0.015*
H37B	0.0889	0.1864	0.4982	0.015*
C38	0.02848 (7)	0.15290 (14)	0.54956 (8)	0.0128 (3)
P1	0.87051 (2)	0.20853 (4)	0.09170 (2)	0.01435 (9)
F1	0.88717 (5)	0.15364 (11)	0.03144 (5)	0.0253 (2)
F2	0.92037 (5)	0.32889 (10)	0.09903 (5)	0.0214 (2)
F3	0.93125 (5)	0.12522 (10)	0.14210 (5)	0.0245 (2)
F4	0.85452 (5)	0.26333 (12)	0.15215 (6)	0.0293 (2)
F5	0.81102 (5)	0.29279 (11)	0.04093 (6)	0.0320 (3)
F6	0.82114 (5)	0.08857 (11)	0.08447 (6)	0.0309 (2)
P2	0.56387 (2)	0.20817 (4)	0.84196 (2)	0.01808 (9)
F7	0.56344 (7)	0.09114 (13)	0.89065 (6)	0.0421 (3)
F8	0.56504 (7)	0.32505 (11)	0.79448 (6)	0.0385 (3)
F9	0.63582 (6)	0.24718 (17)	0.89367 (8)	0.0553 (4)
F10	0.59708 (7)	0.11130 (12)	0.80632 (6)	0.0420 (3)
F11	0.53192 (7)	0.30432 (13)	0.87873 (6)	0.0408 (3)
F12	0.49280 (7)	0.16633 (14)	0.79232 (8)	0.0552 (4)
C1S	0.7245 (10)	0.1996 (18)	0.4578 (10)	0.041 (5)*	0.128 (5)
C2S	0.7208 (12)	0.319 (2)	0.4357 (12)	0.060 (6)*	0.128 (5)
N1S	0.7325 (11)	0.094 (2)	0.4837 (11)	0.069 (6)*	0.128 (5)

	U11	U22	U33	U12	U13	U23
Co1	0.00947 (10)	0.00884 (10)	0.01061 (10)	0.00142 (7)	0.00414 (8)	0.00024 (7)
O1	0.0143 (5)	0.0130 (5)	0.0118 (5)	0.0028 (4)	0.0047 (4)	0.0005 (4)
O2	0.0184 (5)	0.0142 (5)	0.0110 (5)	−0.0002 (4)	0.0015 (4)	−0.0007 (4)
O3	0.0124 (5)	0.0112 (5)	0.0132 (5)	0.0005 (4)	0.0034 (4)	0.0005 (4)
O4	0.0236 (6)	0.0165 (6)	0.0138 (5)	−0.0006 (5)	−0.0001 (5)	0.0005 (4)
N1	0.0135 (6)	0.0101 (6)	0.0105 (6)	0.0026 (5)	0.0028 (5)	0.0005 (4)
N2	0.0104 (6)	0.0097 (6)	0.0105 (6)	0.0011 (4)	0.0030 (5)	−0.0015 (4)
N3	0.0139 (6)	0.0168 (6)	0.0165 (7)	0.0033 (5)	0.0076 (5)	0.0027 (5)
N4	0.0122 (6)	0.0120 (6)	0.0158 (6)	0.0009 (5)	0.0050 (5)	0.0027 (5)
C1	0.0214 (8)	0.0148 (7)	0.0137 (7)	0.0055 (6)	0.0040 (6)	−0.0010 (6)
C2	0.0243 (8)	0.0134 (7)	0.0190 (8)	0.0043 (6)	−0.0030 (7)	−0.0066 (6)
C3	0.0158 (8)	0.0106 (7)	0.0346 (10)	−0.0009 (6)	−0.0024 (7)	−0.0018 (7)
C4	0.0138 (7)	0.0142 (8)	0.0291 (9)	−0.0003 (6)	0.0052 (6)	0.0024 (6)
C5	0.0111 (7)	0.0119 (7)	0.0134 (7)	0.0018 (5)	0.0023 (5)	0.0012 (5)
C6	0.0126 (7)	0.0126 (7)	0.0143 (7)	−0.0001 (5)	0.0065 (6)	0.0007 (6)
C7	0.0110 (7)	0.0146 (7)	0.0111 (7)	0.0028 (5)	0.0011 (5)	−0.0002 (5)
C8	0.0156 (7)	0.0058 (6)	0.0129 (7)	−0.0006 (5)	0.0041 (6)	−0.0010 (5)
C9	0.0149 (7)	0.0113 (7)	0.0141 (7)	0.0021 (5)	0.0043 (6)	−0.0041 (5)
C10	0.0185 (8)	0.0101 (7)	0.0250 (8)	0.0019 (6)	0.0068 (6)	−0.0031 (6)
C11	0.0176 (7)	0.0097 (7)	0.0185 (8)	0.0019 (6)	0.0044 (6)	0.0025 (5)
C12	0.0199 (8)	0.0198 (8)	0.0224 (8)	0.0078 (6)	0.0102 (7)	0.0048 (6)
C13	0.0245 (9)	0.0287 (10)	0.0348 (10)	0.0135 (7)	0.0165 (8)	0.0071 (8)
C14	0.0183 (9)	0.0432 (11)	0.0364 (11)	0.0094 (8)	0.0168 (8)	0.0067 (9)
C15	0.0192 (8)	0.0332 (10)	0.0260 (9)	0.0016 (7)	0.0143 (7)	0.0063 (7)
C16	0.0159 (7)	0.0216 (8)	0.0171 (8)	0.0004 (6)	0.0078 (6)	0.0036 (6)
C17	0.0179 (7)	0.0178 (8)	0.0204 (8)	−0.0022 (6)	0.0106 (6)	0.0038 (6)
C18	0.0128 (7)	0.0146 (7)	0.0153 (7)	−0.0015 (6)	0.0014 (6)	−0.0002 (6)
C19	0.0098 (6)	0.0120 (7)	0.0169 (7)	0.0021 (5)	0.0025 (6)	0.0001 (5)
Co2	0.00870 (10)	0.00702 (10)	0.01076 (10)	0.00047 (6)	0.00437 (7)	0.00104 (6)
O5	0.0113 (5)	0.0097 (5)	0.0129 (5)	0.0006 (4)	0.0019 (4)	−0.0003 (4)
O6	0.0172 (6)	0.0159 (6)	0.0240 (6)	0.0014 (4)	−0.0050 (5)	−0.0001 (5)
O7	0.0097 (5)	0.0122 (5)	0.0175 (5)	−0.0004 (4)	0.0052 (4)	0.0016 (4)
O8	0.0115 (5)	0.0128 (5)	0.0225 (6)	0.0009 (4)	−0.0011 (4)	0.0004 (4)
N5	0.0172 (6)	0.0109 (6)	0.0159 (6)	0.0020 (5)	0.0087 (5)	0.0016 (5)
N6	0.0138 (6)	0.0087 (6)	0.0141 (6)	0.0004 (5)	0.0063 (5)	0.0013 (5)
N7	0.0082 (5)	0.0096 (6)	0.0124 (6)	−0.0003 (4)	0.0030 (5)	0.0014 (4)
N8	0.0088 (5)	0.0090 (6)	0.0116 (6)	0.0006 (4)	0.0038 (5)	0.0001 (4)
C20	0.0247 (8)	0.0125 (7)	0.0202 (8)	0.0029 (6)	0.0124 (7)	0.0018 (6)
C21	0.0446 (11)	0.0164 (8)	0.0269 (9)	0.0030 (7)	0.0230 (8)	−0.0013 (7)
C22	0.0506 (13)	0.0233 (10)	0.0290 (10)	0.0032 (8)	0.0278 (10)	−0.0013 (7)
C23	0.0420 (11)	0.0176 (8)	0.0313 (10)	0.0024 (7)	0.0277 (9)	0.0047 (7)
C24	0.0216 (8)	0.0140 (7)	0.0234 (8)	0.0026 (6)	0.0146 (7)	0.0034 (6)
C25	0.0223 (8)	0.0115 (7)	0.0221 (8)	0.0003 (6)	0.0145 (7)	0.0033 (6)
C26	0.0191 (7)	0.0105 (7)	0.0136 (7)	0.0021 (6)	0.0033 (6)	0.0021 (5)
C27	0.0177 (7)	0.0097 (7)	0.0126 (7)	0.0012 (5)	0.0026 (6)	−0.0025 (5)
C28	0.0158 (7)	0.0080 (6)	0.0166 (7)	−0.0011 (5)	0.0051 (6)	−0.0011 (5)
C29	0.0182 (7)	0.0092 (7)	0.0174 (7)	0.0018 (5)	0.0068 (6)	−0.0006 (5)
C30	0.0114 (7)	0.0102 (7)	0.0163 (7)	0.0032 (5)	0.0051 (6)	−0.0008 (5)
C31	0.0105 (6)	0.0117 (7)	0.0147 (7)	0.0004 (5)	0.0039 (5)	−0.0006 (5)
C32	0.0131 (7)	0.0112 (7)	0.0164 (7)	0.0023 (5)	0.0032 (6)	−0.0001 (5)
C33	0.0213 (8)	0.0116 (7)	0.0162 (7)	0.0005 (6)	0.0069 (6)	0.0034 (6)
C34	0.0205 (8)	0.0149 (7)	0.0205 (8)	0.0013 (6)	0.0122 (6)	0.0034 (6)
C35	0.0100 (6)	0.0114 (7)	0.0134 (7)	−0.0006 (5)	0.0045 (5)	−0.0012 (5)
C36	0.0113 (7)	0.0108 (7)	0.0166 (7)	−0.0002 (5)	0.0074 (6)	0.0019 (5)
C37	0.0114 (7)	0.0131 (7)	0.0116 (7)	−0.0005 (5)	0.0020 (5)	−0.0003 (5)
C38	0.0123 (7)	0.0055 (6)	0.0192 (7)	−0.0001 (5)	0.0045 (6)	0.0020 (5)
P1	0.01266 (19)	0.0157 (2)	0.0164 (2)	−0.00268 (14)	0.00746 (16)	−0.00115 (14)
F1	0.0283 (5)	0.0311 (6)	0.0205 (5)	−0.0050 (4)	0.0138 (4)	−0.0074 (4)
F2	0.0183 (5)	0.0168 (5)	0.0318 (5)	−0.0049 (4)	0.0125 (4)	−0.0017 (4)
F3	0.0234 (5)	0.0265 (5)	0.0243 (5)	0.0032 (4)	0.0100 (4)	0.0101 (4)
F4	0.0286 (6)	0.0389 (6)	0.0290 (6)	−0.0046 (5)	0.0206 (5)	−0.0105 (5)
F5	0.0156 (5)	0.0417 (7)	0.0368 (7)	0.0072 (4)	0.0082 (5)	0.0138 (5)
F6	0.0281 (6)	0.0280 (6)	0.0400 (6)	−0.0157 (5)	0.0171 (5)	−0.0052 (5)
P2	0.0187 (2)	0.0220 (2)	0.0166 (2)	0.00141 (15)	0.01012 (17)	0.00088 (15)
F7	0.0496 (8)	0.0452 (7)	0.0451 (7)	0.0207 (6)	0.0332 (6)	0.0262 (6)
F8	0.0730 (9)	0.0196 (5)	0.0417 (7)	0.0028 (6)	0.0428 (7)	0.0037 (5)
F9	0.0223 (6)	0.0543 (8)	0.0703 (10)	0.0002 (6)	−0.0028 (6)	−0.0132 (8)
F10	0.0770 (9)	0.0252 (6)	0.0433 (7)	0.0162 (6)	0.0447 (7)	0.0068 (5)
F11	0.0529 (8)	0.0519 (8)	0.0260 (6)	0.0294 (6)	0.0246 (6)	0.0077 (5)
F12	0.0358 (7)	0.0416 (8)	0.0599 (9)	−0.0092 (6)	−0.0123 (7)	0.0032 (7)

Co1—O1	1.8828 (11)	O6—C27	1.219 (2)
Co1—O3	1.8899 (11)	O7—C38	1.2971 (19)
Co1—N1	1.9484 (13)	O8—C38	1.2246 (18)
Co1—N2	1.9625 (12)	N5—C20	1.347 (2)
Co1—N3	1.9397 (13)	N5—C24	1.347 (2)
Co1—N4	1.9641 (13)	N6—C26	1.4974 (19)
O1—C8	1.2973 (18)	N6—C28	1.4980 (19)
O2—C8	1.2265 (18)	N6—C25	1.4995 (19)
O3—C19	1.3035 (19)	N7—C31	1.3454 (18)
O4—C19	1.2201 (19)	N7—C35	1.3503 (19)
N1—C1	1.3446 (19)	N8—C30	1.4915 (18)
N1—C5	1.353 (2)	N8—C36	1.4981 (18)
N2—C9	1.4957 (18)	N8—C37	1.5026 (18)
N2—C7	1.4985 (18)	C20—C21	1.386 (2)
N2—C6	1.5019 (19)	C20—H20A	0.9500
N3—C16	1.348 (2)	C21—C22	1.380 (3)
N3—C12	1.353 (2)	C21—H21A	0.9500
N4—C11	1.4956 (19)	C22—C23	1.389 (3)
N4—C17	1.4986 (19)	C22—H22A	0.9500
N4—C18	1.4979 (19)	C23—C24	1.391 (2)
C1—C2	1.381 (2)	C23—H23A	0.9500
C1—H1A	0.9500	C24—C25	1.506 (2)
C2—C3	1.382 (3)	C25—H25A	0.9900
C2—H2A	0.9500	C25—H25B	0.9900
C3—C4	1.387 (2)	C26—C27	1.525 (2)
C3—H3A	0.9500	C26—H26A	0.9900
C4—C5	1.381 (2)	C26—H26B	0.9900
C4—H4A	0.9500	C28—C29	1.529 (2)
C5—C6	1.494 (2)	C28—H28A	0.9900
C6—H6A	0.9900	C28—H28B	0.9900
C6—H6B	0.9900	C29—C30	1.531 (2)
C7—C8	1.522 (2)	C29—H29A	0.9900
C7—H7A	0.9900	C29—H29B	0.9900
C7—H7B	0.9900	C30—H30A	0.9900
C9—C10	1.520 (2)	C30—H30B	0.9900
C9—H9A	0.9900	C31—C32	1.382 (2)
C9—H9B	0.9900	C31—H31A	0.9500
C10—C11	1.529 (2)	C32—C33	1.380 (2)
C10—H10A	0.9900	C32—H32A	0.9500
C10—H10B	0.9900	C33—C34	1.390 (2)
C11—H11A	0.9900	C33—H33A	0.9500
C11—H11B	0.9900	C34—C35	1.378 (2)
C12—C13	1.387 (2)	C34—H34A	0.9500
C12—H12A	0.9500	C35—C36	1.492 (2)
C13—C14	1.381 (3)	C36—H36A	0.9900
C13—H13A	0.9500	C36—H36B	0.9900
C14—C15	1.388 (3)	C37—C38	1.525 (2)
C14—H14A	0.9500	C37—H37A	0.9900
C15—C16	1.390 (2)	C37—H37B	0.9900
C15—H15A	0.9500	P1—F4	1.5979 (11)
C16—C17	1.499 (2)	P1—F5	1.5985 (11)
C17—H17A	0.9900	P1—F6	1.6024 (11)
C17—H17B	0.9900	P1—F1	1.6023 (10)
C18—C19	1.524 (2)	P1—F3	1.6052 (10)
C18—H18A	0.9900	P1—F2	1.6120 (10)
C18—H18B	0.9900	P2—F12	1.5734 (13)
Co2—O5	1.8875 (10)	P2—F8	1.5924 (12)
Co2—O7	1.8830 (11)	P2—F9	1.5941 (14)
Co2—N5	1.9403 (13)	P2—F11	1.5952 (11)
Co2—N6	1.9654 (12)	P2—F10	1.6007 (12)
Co2—N7	1.9575 (12)	P2—F7	1.6069 (12)
Co2—N8	1.9645 (12)	C1S—N1S	1.20 (3)
O5—C27	1.3054 (18)	C1S—C2S	1.30 (3)
O1—Co1—O3	178.47 (5)	C38—O7—Co2	114.38 (9)
O1—Co1—N3	93.10 (5)	C20—N5—C24	119.71 (14)
O3—Co1—N3	87.98 (5)	C20—N5—Co2	125.75 (11)
O1—Co1—N1	86.51 (5)	C24—N5—Co2	113.71 (11)
O3—Co1—N1	94.41 (5)	C26—N6—C28	111.73 (11)
N3—Co1—N1	98.52 (6)	C26—N6—C25	110.69 (12)
O1—Co1—N2	88.81 (5)	C28—N6—C25	107.94 (11)
O3—Co1—N2	90.09 (5)	C26—N6—Co2	107.70 (9)
N3—Co1—N2	177.94 (5)	C28—N6—Co2	114.04 (9)
N1—Co1—N2	82.36 (5)	C25—N6—Co2	104.52 (9)
O1—Co1—N4	91.25 (5)	C31—N7—C35	119.02 (13)
O3—Co1—N4	87.79 (5)	C31—N7—Co2	127.02 (10)
N3—Co1—N4	83.28 (6)	C35—N7—Co2	113.15 (10)
N1—Co1—N4	177.20 (5)	C30—N8—C36	107.28 (11)
N2—Co1—N4	95.91 (5)	C30—N8—C37	112.37 (11)
C8—O1—Co1	114.32 (9)	C36—N8—C37	110.53 (11)
C19—O3—Co1	115.11 (10)	C30—N8—Co2	115.23 (9)
C1—N1—C5	118.88 (13)	C36—N8—Co2	104.29 (9)
C1—N1—Co1	127.31 (11)	C37—N8—Co2	106.83 (9)
C5—N1—Co1	113.23 (10)	N5—C20—C21	121.52 (15)
C9—N2—C7	112.00 (11)	N5—C20—H20A	119.2
C9—N2—C6	106.84 (11)	C21—C20—H20A	119.2
C7—N2—C6	111.28 (11)	C22—C21—C20	118.90 (17)
C9—N2—Co1	115.61 (9)	C22—C21—H21A	120.6
C7—N2—Co1	106.74 (9)	C20—C21—H21A	120.6
C6—N2—Co1	104.15 (9)	C21—C22—C23	119.84 (17)
C16—N3—C12	119.65 (14)	C21—C22—H22A	120.1
C16—N3—Co1	113.47 (11)	C23—C22—H22A	120.1
C12—N3—Co1	126.30 (11)	C22—C23—C24	118.51 (16)
C11—N4—C17	107.94 (12)	C22—C23—H23A	120.7
C11—N4—C18	111.85 (12)	C24—C23—H23A	120.7
C17—N4—C18	110.95 (12)	N5—C24—C23	121.49 (16)
C11—N4—Co1	113.66 (9)	N5—C24—C25	113.32 (13)
C17—N4—Co1	104.33 (9)	C23—C24—C25	125.10 (15)
C18—N4—Co1	107.87 (9)	N6—C25—C24	106.63 (12)
N1—C1—C2	121.78 (15)	N6—C25—H25A	110.4
N1—C1—H1A	119.1	C24—C25—H25A	110.4
C2—C1—H1A	119.1	N6—C25—H25B	110.4
C3—C2—C1	119.25 (15)	C24—C25—H25B	110.4
C3—C2—H2A	120.4	H25A—C25—H25B	108.6
C1—C2—H2A	120.4	N6—C26—C27	111.79 (12)
C2—C3—C4	119.25 (15)	N6—C26—H26A	109.3
C2—C3—H3A	120.4	C27—C26—H26A	109.3
C4—C3—H3A	120.4	N6—C26—H26B	109.3
C5—C4—C3	118.74 (16)	C27—C26—H26B	109.3
C5—C4—H4A	120.6	H26A—C26—H26B	107.9
C3—C4—H4A	120.6	O6—C27—O5	123.80 (14)
N1—C5—C4	121.92 (14)	O6—C27—C26	120.27 (14)
N1—C5—C6	113.41 (13)	O5—C27—C26	115.93 (13)
C4—C5—C6	124.54 (14)	N6—C28—C29	114.68 (12)
C5—C6—N2	107.00 (12)	N6—C28—H28A	108.6
C5—C6—H6A	110.3	C29—C28—H28A	108.6
N2—C6—H6A	110.3	N6—C28—H28B	108.6
C5—C6—H6B	110.3	C29—C28—H28B	108.6
N2—C6—H6B	110.3	H28A—C28—H28B	107.6
H6A—C6—H6B	108.6	C28—C29—C30	117.49 (12)
N2—C7—C8	112.54 (12)	C28—C29—H29A	107.9
N2—C7—H7A	109.1	C30—C29—H29A	107.9
C8—C7—H7A	109.1	C28—C29—H29B	107.9
N2—C7—H7B	109.1	C30—C29—H29B	107.9
C8—C7—H7B	109.1	H29A—C29—H29B	107.2
H7A—C7—H7B	107.8	N8—C30—C29	115.23 (12)
O2—C8—O1	123.87 (14)	N8—C30—H30A	108.5
O2—C8—C7	119.39 (13)	C29—C30—H30A	108.5
O1—C8—C7	116.74 (12)	N8—C30—H30B	108.5
N2—C9—C10	115.42 (12)	C29—C30—H30B	108.5
N2—C9—H9A	108.4	H30A—C30—H30B	107.5
C10—C9—H9A	108.4	N7—C31—C32	121.68 (14)
N2—C9—H9B	108.4	N7—C31—H31A	119.2
C10—C9—H9B	108.4	C32—C31—H31A	119.2
H9A—C9—H9B	107.5	C31—C32—C33	119.29 (14)
C9—C10—C11	117.25 (13)	C31—C32—H32A	120.4
C9—C10—H10A	108.0	C33—C32—H32A	120.4
C11—C10—H10A	108.0	C32—C33—C34	119.12 (14)
C9—C10—H10B	108.0	C32—C33—H33A	120.4
C11—C10—H10B	108.0	C34—C33—H33A	120.4
H10A—C10—H10B	107.2	C35—C34—C33	118.84 (14)
N4—C11—C10	115.36 (13)	C35—C34—H34A	120.6
N4—C11—H11A	108.4	C33—C34—H34A	120.6
C10—C11—H11A	108.4	N7—C35—C34	121.93 (14)
N4—C11—H11B	108.4	N7—C35—C36	113.50 (13)
C10—C11—H11B	108.4	C34—C35—C36	124.43 (13)
H11A—C11—H11B	107.5	C35—C36—N8	107.17 (11)
N3—C12—C13	121.08 (16)	C35—C36—H36A	110.3
N3—C12—H12A	119.5	N8—C36—H36A	110.3
C13—C12—H12A	119.5	C35—C36—H36B	110.3
C14—C13—C12	119.38 (17)	N8—C36—H36B	110.3
C14—C13—H13A	120.3	H36A—C36—H36B	108.5
C12—C13—H13A	120.3	N8—C37—C38	112.29 (12)
C13—C14—C15	119.48 (17)	N8—C37—H37A	109.1
C13—C14—H14A	120.3	C38—C37—H37A	109.1
C15—C14—H14A	120.3	N8—C37—H37B	109.1
C14—C15—C16	118.69 (17)	C38—C37—H37B	109.1
C14—C15—H15A	120.7	H37A—C37—H37B	107.9
C16—C15—H15A	120.7	O8—C38—O7	123.82 (14)
N3—C16—C15	121.58 (16)	O8—C38—C37	119.50 (14)
N3—C16—C17	113.48 (13)	O7—C38—C37	116.67 (12)
C15—C16—C17	124.89 (15)	F4—P1—F5	90.40 (7)
N4—C17—C16	106.96 (12)	F4—P1—F6	89.70 (6)
N4—C17—H17A	110.3	F5—P1—F6	90.47 (6)
C16—C17—H17A	110.3	F4—P1—F1	179.54 (6)
N4—C17—H17B	110.3	F5—P1—F1	89.96 (6)
C16—C17—H17B	110.3	F6—P1—F1	90.57 (6)
H17A—C17—H17B	108.6	F4—P1—F3	90.27 (6)
N4—C18—C19	111.33 (12)	F5—P1—F3	178.85 (6)
N4—C18—H18A	109.4	F6—P1—F3	90.46 (6)
C19—C18—H18A	109.4	F1—P1—F3	89.36 (6)
N4—C18—H18B	109.4	F4—P1—F2	90.37 (6)
C19—C18—H18B	109.4	F5—P1—F2	89.69 (6)
H18A—C18—H18B	108.0	F6—P1—F2	179.82 (6)
O4—C19—O3	123.95 (14)	F1—P1—F2	89.35 (6)
O4—C19—C18	120.04 (13)	F3—P1—F2	89.38 (5)
O3—C19—C18	116.00 (13)	F12—P2—F8	90.83 (8)
O7—Co2—O5	178.36 (5)	F12—P2—F9	178.31 (9)
O7—Co2—N5	93.48 (5)	F8—P2—F9	90.86 (9)
O5—Co2—N5	87.72 (5)	F12—P2—F11	90.45 (9)
O7—Co2—N7	86.39 (5)	F8—P2—F11	89.32 (6)
O5—Co2—N7	94.55 (5)	F9—P2—F11	89.53 (8)
N5—Co2—N7	98.55 (5)	F12—P2—F10	90.47 (9)
O7—Co2—N8	88.69 (5)	F8—P2—F10	91.19 (6)
O5—Co2—N8	90.09 (5)	F9—P2—F10	89.54 (8)
N5—Co2—N8	177.67 (5)	F11—P2—F10	178.94 (8)
N7—Co2—N8	82.39 (5)	F12—P2—F7	89.87 (8)
O7—Co2—N6	91.07 (5)	F8—P2—F7	179.26 (9)
O5—Co2—N6	87.96 (5)	F9—P2—F7	88.44 (9)
N5—Co2—N6	83.23 (5)	F11—P2—F7	90.43 (7)
N7—Co2—N6	176.98 (5)	F10—P2—F7	89.04 (6)
N8—Co2—N6	95.92 (5)	N1S—C1S—C2S	174 (2)
C27—O5—Co2	115.33 (10)
O3—Co1—O1—C8	−53.5 (19)	O7—Co2—O5—C27	−51.5 (17)
N3—Co1—O1—C8	171.78 (10)	N5—Co2—O5—C27	85.46 (11)
N1—Co1—O1—C8	73.42 (10)	N7—Co2—O5—C27	−176.14 (10)
N2—Co1—O1—C8	−9.00 (10)	N8—Co2—O5—C27	−93.77 (10)
N4—Co1—O1—C8	−104.89 (10)	N6—Co2—O5—C27	2.16 (10)
O1—Co1—O3—C19	−47.7 (19)	O5—Co2—O7—C38	−52.4 (17)
N3—Co1—O3—C19	87.11 (11)	N5—Co2—O7—C38	170.64 (10)
N1—Co1—O3—C19	−174.50 (10)	N7—Co2—O7—C38	72.28 (10)
N2—Co1—O3—C19	−92.15 (10)	N8—Co2—O7—C38	−10.18 (10)
N4—Co1—O3—C19	3.76 (10)	N6—Co2—O7—C38	−106.08 (10)
O1—Co1—N1—C1	59.18 (13)	O7—Co2—N5—C20	−117.75 (13)
O3—Co1—N1—C1	−122.05 (13)	O5—Co2—N5—C20	63.37 (13)
N3—Co1—N1—C1	−33.44 (13)	N7—Co2—N5—C20	−30.88 (14)
N2—Co1—N1—C1	148.45 (13)	N8—Co2—N5—C20	82.9 (14)
N4—Co1—N1—C1	96.2 (11)	N6—Co2—N5—C20	151.59 (14)
O1—Co1—N1—C5	−111.91 (10)	O7—Co2—N5—C24	72.84 (12)
O3—Co1—N1—C5	66.86 (10)	O5—Co2—N5—C24	−106.03 (12)
N3—Co1—N1—C5	155.48 (10)	N7—Co2—N5—C24	159.71 (11)
N2—Co1—N1—C5	−22.64 (10)	N8—Co2—N5—C24	−86.5 (14)
N4—Co1—N1—C5	−74.9 (11)	N6—Co2—N5—C24	−17.82 (11)
O1—Co1—N2—C9	−119.10 (10)	O7—Co2—N6—C26	−176.35 (9)
O3—Co1—N2—C9	59.83 (10)	O5—Co2—N6—C26	4.98 (9)
N3—Co1—N2—C9	38.8 (16)	N5—Co2—N6—C26	−82.97 (10)
N1—Co1—N2—C9	154.26 (10)	N7—Co2—N6—C26	150.9 (9)
N4—Co1—N2—C9	−27.96 (10)	N8—Co2—N6—C26	94.86 (9)
O1—Co1—N2—C7	6.21 (9)	O7—Co2—N6—C28	59.05 (10)
O3—Co1—N2—C7	−174.87 (9)	O5—Co2—N6—C28	−119.62 (10)
N3—Co1—N2—C7	164.1 (15)	N5—Co2—N6—C28	152.43 (10)
N1—Co1—N2—C7	−80.43 (9)	N7—Co2—N6—C28	26.3 (10)
N4—Co1—N2—C7	97.34 (9)	N8—Co2—N6—C28	−29.74 (10)
O1—Co1—N2—C6	124.02 (9)	O7—Co2—N6—C25	−58.59 (9)
O3—Co1—N2—C6	−57.05 (9)	O5—Co2—N6—C25	122.74 (9)
N3—Co1—N2—C6	−78.1 (15)	N5—Co2—N6—C25	34.79 (9)
N1—Co1—N2—C6	37.38 (9)	N7—Co2—N6—C25	−91.3 (10)
N4—Co1—N2—C6	−144.85 (9)	N8—Co2—N6—C25	−147.38 (9)
O1—Co1—N3—C16	72.52 (12)	O7—Co2—N7—C31	59.07 (12)
O3—Co1—N3—C16	−106.39 (12)	O5—Co2—N7—C31	−122.29 (12)
N1—Co1—N3—C16	159.45 (11)	N5—Co2—N7—C31	−33.91 (13)
N2—Co1—N3—C16	−85.4 (15)	N8—Co2—N7—C31	148.23 (13)
N4—Co1—N3—C16	−18.37 (11)	N6—Co2—N7—C31	91.9 (10)
O1—Co1—N3—C12	−116.33 (14)	O7—Co2—N7—C35	−110.35 (10)
O3—Co1—N3—C12	64.76 (14)	O5—Co2—N7—C35	68.29 (10)
N1—Co1—N3—C12	−29.40 (15)	N5—Co2—N7—C35	156.66 (10)
N2—Co1—N3—C12	85.8 (16)	N8—Co2—N7—C35	−21.19 (10)
N4—Co1—N3—C12	152.78 (15)	N6—Co2—N7—C35	−77.6 (10)
O1—Co1—N4—C11	59.21 (10)	O7—Co2—N8—C30	−119.56 (10)
O3—Co1—N4—C11	−119.60 (10)	O5—Co2—N8—C30	59.34 (10)
N3—Co1—N4—C11	152.18 (11)	N5—Co2—N8—C30	39.8 (14)
N1—Co1—N4—C11	22.2 (12)	N7—Co2—N8—C30	153.91 (10)
N2—Co1—N4—C11	−29.73 (11)	N6—Co2—N8—C30	−28.62 (10)
O1—Co1—N4—C17	−58.12 (9)	O7—Co2—N8—C36	123.12 (9)
O3—Co1—N4—C17	123.08 (9)	O5—Co2—N8—C36	−57.98 (9)
N3—Co1—N4—C17	34.86 (9)	N5—Co2—N8—C36	−77.5 (14)
N1—Co1—N4—C17	−95.1 (11)	N7—Co2—N8—C36	36.59 (9)
N2—Co1—N4—C17	−147.05 (9)	N6—Co2—N8—C36	−145.94 (9)
O1—Co1—N4—C18	−176.16 (9)	O7—Co2—N8—C37	6.05 (9)
O3—Co1—N4—C18	5.04 (9)	O5—Co2—N8—C37	−175.06 (9)
N3—Co1—N4—C18	−83.19 (10)	N5—Co2—N8—C37	165.4 (13)
N1—Co1—N4—C18	146.9 (11)	N7—Co2—N8—C37	−80.48 (9)
N2—Co1—N4—C18	94.90 (10)	N6—Co2—N8—C37	96.98 (9)
C5—N1—C1—C2	−3.7 (2)	C24—N5—C20—C21	−2.2 (2)
Co1—N1—C1—C2	−174.38 (12)	Co2—N5—C20—C21	−171.04 (14)
N1—C1—C2—C3	0.1 (2)	N5—C20—C21—C22	1.6 (3)
C1—C2—C3—C4	2.5 (2)	C20—C21—C22—C23	−0.4 (3)
C2—C3—C4—C5	−1.4 (2)	C21—C22—C23—C24	−0.2 (3)
C1—N1—C5—C4	4.8 (2)	C20—N5—C24—C23	1.6 (2)
Co1—N1—C5—C4	176.75 (12)	Co2—N5—C24—C23	171.75 (14)
C1—N1—C5—C6	−171.34 (13)	C20—N5—C24—C25	−175.09 (14)
Co1—N1—C5—C6	0.57 (15)	Co2—N5—C24—C25	−4.98 (17)
C3—C4—C5—N1	−2.3 (2)	C22—C23—C24—N5	−0.5 (3)
C3—C4—C5—C6	173.47 (15)	C22—C23—C24—C25	175.88 (18)
N1—C5—C6—N2	30.38 (16)	C26—N6—C25—C24	70.86 (15)
C4—C5—C6—N2	−145.69 (15)	C28—N6—C25—C24	−166.58 (12)
C9—N2—C6—C5	−168.43 (11)	Co2—N6—C25—C24	−44.83 (13)
C7—N2—C6—C5	69.04 (14)	N5—C24—C25—N6	33.63 (18)
Co1—N2—C6—C5	−45.60 (12)	C23—C24—C25—N6	−142.96 (17)
C9—N2—C7—C8	124.42 (13)	C28—N6—C26—C27	115.70 (13)
C6—N2—C7—C8	−116.07 (13)	C25—N6—C26—C27	−123.98 (13)
Co1—N2—C7—C8	−3.05 (14)	Co2—N6—C26—C27	−10.28 (14)
Co1—O1—C8—O2	−171.62 (11)	Co2—O5—C27—O6	172.00 (13)
Co1—O1—C8—C7	9.16 (16)	Co2—O5—C27—C26	−8.93 (16)
N2—C7—C8—O2	176.96 (12)	N6—C26—C27—O6	−167.91 (14)
N2—C7—C8—O1	−3.79 (18)	N6—C26—C27—O5	12.98 (18)
C7—N2—C9—C10	−61.72 (16)	C26—N6—C28—C29	−58.19 (16)
C6—N2—C9—C10	176.19 (12)	C25—N6—C28—C29	179.89 (12)
Co1—N2—C9—C10	60.83 (15)	Co2—N6—C28—C29	64.23 (14)
N2—C9—C10—C11	−30.47 (19)	N6—C28—C29—C30	−35.32 (18)
C17—N4—C11—C10	179.54 (13)	C36—N8—C30—C29	177.06 (12)
C18—N4—C11—C10	−58.13 (17)	C37—N8—C30—C29	−61.25 (16)
Co1—N4—C11—C10	64.34 (15)	Co2—N8—C30—C29	61.44 (14)
C9—C10—C11—N4	−35.5 (2)	C28—C29—C30—N8	−30.78 (19)
C16—N3—C12—C13	−3.6 (3)	C35—N7—C31—C32	−3.3 (2)
Co1—N3—C12—C13	−174.26 (14)	Co2—N7—C31—C32	−172.13 (11)
N3—C12—C13—C14	2.0 (3)	N7—C31—C32—C33	0.3 (2)
C12—C13—C14—C15	1.5 (3)	C31—C32—C33—C34	1.6 (2)
C13—C14—C15—C16	−3.4 (3)	C32—C33—C34—C35	−0.6 (2)
C12—N3—C16—C15	1.6 (2)	C31—N7—C35—C34	4.4 (2)
Co1—N3—C16—C15	173.45 (13)	Co2—N7—C35—C34	174.75 (12)
C12—N3—C16—C17	−175.99 (14)	C31—N7—C35—C36	−171.45 (13)
Co1—N3—C16—C17	−4.20 (17)	Co2—N7—C35—C36	−1.10 (15)
C14—C15—C16—N3	1.8 (3)	C33—C34—C35—N7	−2.5 (2)
C14—C15—C16—C17	179.20 (17)	C33—C34—C35—C36	172.89 (14)
C11—N4—C17—C16	−165.84 (13)	N7—C35—C36—N8	31.48 (16)
C18—N4—C17—C16	71.27 (15)	C34—C35—C36—N8	−144.25 (15)
Co1—N4—C17—C16	−44.64 (13)	C30—N8—C36—C35	−168.29 (11)
N3—C16—C17—N4	33.05 (18)	C37—N8—C36—C35	68.88 (14)
C15—C16—C17—N4	−144.50 (16)	Co2—N8—C36—C35	−45.61 (12)
C11—N4—C18—C19	114.02 (14)	C30—N8—C37—C38	125.51 (13)
C17—N4—C18—C19	−125.39 (13)	C36—N8—C37—C38	−114.67 (13)
Co1—N4—C18—C19	−11.69 (14)	Co2—N8—C37—C38	−1.80 (14)
Co1—O3—C19—O4	169.65 (12)	Co2—O7—C38—O8	−169.73 (12)
Co1—O3—C19—C18	−11.81 (16)	Co2—O7—C38—C37	11.39 (16)
N4—C18—C19—O4	−165.58 (13)	N8—C37—C38—O8	174.96 (13)
N4—C18—C19—O3	15.81 (18)	N8—C37—C38—O7	−6.12 (18)

Table 1

Selected bond lengths (Å)

Co1—O1	1.8828 (11)
Co1—O3	1.8899 (11)
Co1—N1	1.9484 (13)
Co1—N2	1.9625 (12)
Co1—N3	1.9397 (13)
Co1—N4	1.9641 (13)
Co2—O5	1.8875 (10)
Co2—O7	1.8830 (11)
Co2—N5	1.9403 (13)
Co2—N6	1.9654 (12)
Co2—N7	1.9575 (12)
Co2—N8	1.9645 (12)