Literature DB >> 23695586

(Sub-)femtosecond control of molecular reactions via tailoring the electric field of light.

Matthias F Kling1, Philipp von den Hoff, Irina Znakovskaya, Regina de Vivie-Riedle.   

Abstract

We review recent progress in the control over chemical reactions by employing tailored electric field waveforms of intense laser pulses. The sub-cycle tailoring of such waveforms permits the control of electron dynamics in molecules on sub-femtosecond timescales. We show that laser-driven electron dynamics in molecules has the potential to control chemical reactions. In the presence of strong fields, electron and nuclear motion are coupled, requiring models beyond the Born-Oppenheimer approximation for their theoretical treatment. Various mechanisms for the lightwave control of molecular reactions are described, and their relevance for the control of diatomic molecular reactions is discussed. Rapid experimental and theoretical progress is currently being made, indicating that attosecond controlled chemistry is within reach.

Entities:  

Year:  2013        PMID: 23695586     DOI: 10.1039/c3cp50591j

Source DB:  PubMed          Journal:  Phys Chem Chem Phys        ISSN: 1463-9076            Impact factor:   3.676


  2 in total

1.  Duration of an intense laser pulse can determine the breakage of multiple chemical bonds.

Authors:  Xinhua Xie; Erik Lötstedt; Stefan Roither; Markus Schöffler; Daniil Kartashov; Katsumi Midorikawa; Andrius Baltuška; Kaoru Yamanouchi; Markus Kitzler
Journal:  Sci Rep       Date:  2015-08-14       Impact factor: 4.379

2.  Carrier-envelope phase dependence of the directional fragmentation and hydrogen migration in toluene in few-cycle laser fields.

Authors:  Hui Li; Nora G Kling; Benjamin Förg; Johannes Stierle; Alexander Kessel; Sergei A Trushin; Matthias F Kling; Spyros Kaziannis
Journal:  Struct Dyn       Date:  2016-02-17       Impact factor: 2.920

  2 in total

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