Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Cp*Rh-based heterometallic metallarectangles: size-dependent Borromean link structures and catalytic acyl transfer.

Literature DB >> 23678944

Cp*Rh-based heterometallic metallarectangles: size-dependent Borromean link structures and catalytic acyl transfer.

Sheng-Li Huang¹, Yue-Jian Lin, T S Andy Hor, Guo-Xin Jin.

Abstract

A series of Cp*Rh-based functional metallarectangles have been synthesized from metallaligands. Enlargement of one linker leads to the isolation of two novel Borromean link architectures. All these complexes are intact in solution, as evident from ESI-MS spectroscopic analysis. Arising from the combination of open Cu centers and favorable cavity space, {(Cp*Rh)4(bpe)2[Cu(opba)·2MeOH]2}4(OTf)·6MeOH shows extraordinary catalytic abilities with high efficiency and wide substrate selectivity in the acyl-transfer reaction.

Entities: Chemical

Mesh：

Substances：

Year: 2013 PMID： 23678944 DOI： 10.1021/ja402630g

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

Keyword Cloud
Cited

12 in total

1. An infinite chainmail of M6L6 metallacycles featuring multiple Borromean links.

Authors: Flora L Thorp-Greenwood; Alexander N Kulak; Michaele J Hardie
Journal: Nat Chem Date: 2015-05-04 Impact factor: 24.427

2. A Star of David catenane.

Authors: David A Leigh; Robin G Pritchard; Alexander J Stephens
Journal: Nat Chem Date: 2014-09-21 Impact factor: 24.427

3. A Solomon link through an interwoven molecular grid.

Authors: Jonathon E Beves; Jonathan J Danon; David A Leigh; Jean-François Lemonnier; Iñigo J Vitorica-Yrezabal
Journal: Angew Chem Int Ed Engl Date: 2015-05-08 Impact factor: 15.336

4. Catenanes: fifty years of molecular links.

Authors: Guzmán Gil-Ramírez; David A Leigh; Alexander J Stephens
Journal: Angew Chem Int Ed Engl Date: 2015-05-07 Impact factor: 15.336

5. Large, heterometallic coordination cages based on ditopic metallo-ligands with 3-pyridyl donor groups.

Authors: Matthew D Wise; Julian J Holstein; Philip Pattison; Celine Besnard; Euro Solari; Rosario Scopelliti; Gerard Bricogne; Kay Severin
Journal: Chem Sci Date: 2014-11-11 Impact factor: 9.825

6. Synthesis, Molecular Structure and Cytotoxicity of Molecular Materials Based on Water Soluble Half-Sandwich Rh(III) and Ir(III) Tetranuclear Metalla-Cycles.

Authors: Gajendra Gupta; Benjamin S Murray; Paul J Dyson; Bruno Therrien
Journal: Materials (Basel) Date: 2013-11-20 Impact factor: 3.623

Cp*Rh-based heterometallic metallarectangles: size-dependent Borromean link structures and catalytic acyl transfer.

1. An infinite chainmail of M6L6 metallacycles featuring multiple Borromean links.

2. A Star of David catenane.

3. A Solomon link through an interwoven molecular grid.

4. Catenanes: fifty years of molecular links.

5. Large, heterometallic coordination cages based on ditopic metallo-ligands with 3-pyridyl donor groups.

6. Synthesis, Molecular Structure and Cytotoxicity of Molecular Materials Based on Water Soluble Half-Sandwich Rh(III) and Ir(III) Tetranuclear Metalla-Cycles.

7. Synthesizing topological structures containing RNA.

8. A Six-Crossing Doubly Interlocked [2]Catenane with Twisted Rings, and a Molecular Granny Knot.

9. Coordination Chemistry of a Molecular Pentafoil Knot.

10. Design and self-assembly of hexahedral coordination cages for cascade reactions.