Literature DB >> 23663171

Rhodium(III)-catalyzed azacycle-directed intermolecular insertion of arene C-H bonds into α-diazocarbonyl compounds.

Xinzhang Yu1, Songjie Yu, Jian Xiao, Boshun Wan, Xingwei Li.   

Abstract

Cp*Rh(III)-catalyzed intermolecular C-C couplings between activated α-diazocarbonyl compounds and arenes bearing a range of azacyclic directing groups have been achieved. This catalytic alkylation reaction operates under mild conditions with good functional group tolerance.

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Year:  2013        PMID： 23663171     DOI： 10.1021/jo400572h

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  6 in total

1.  Rhodium(III)-catalyzed C-H functionalization of C-alkenyl azoles with sulfoxonium ylides for the synthesis of bridgehead N-fused [5,6]-bicyclic heterocycles.

Authors:  Gia L Hoang; Jonathan A Ellman
Journal:  Tetrahedron       Date:  2018-03-31       Impact factor: 2.457

2.  Regioselective Arene C-H Alkylation Enabled by Organic Photoredox Catalysis.

Authors:  Natalie Holmberg-Douglas; Nicholas P R Onuska; David A Nicewicz
Journal:  Angew Chem Int Ed Engl       Date:  2020-03-17       Impact factor: 15.336

3.  Direct Synthesis of 5-Aryl Barbituric Acids by Rhodium(II)-Catalyzed Reactions of Arenes with Diazo Compounds.

Authors:  Daniel Best; David J Burns; Hon Wai Lam
Journal:  Angew Chem Int Ed Engl       Date:  2015-05-08       Impact factor: 15.336

4.  Tri-μ-chlorido-bis-[(η(5)-penta-methyl-cyclo-penta-dien-yl)rhodium(III)] hexa-fluorido-phosphate from synchrotron radiation.

Authors:  Lida Ezzedinloo; Sumi Shrestha; Mohan Bhadbhade; Stephen Colbran
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-12-11

5.  Rhodium-Catalyzed C-H Methylation and Alkylation Reactions by Carbene-Transfer Reactions.

Authors:  Claire Empel; Sripati Jana; Tim Langletz; Rene M Koenigs
Journal:  Chemistry       Date:  2022-02-02       Impact factor: 5.020

6.  Rhodium-catalyzed regioselective addition of the ortho C-H bond in aromatic amides to the C-C double bond in α,β-unsaturated γ-lactones and dihydrofurans.

Authors:  Kaname Shibata; Naoto Chatani
Journal:  Chem Sci       Date:  2015-09-25       Impact factor: 9.825
  6 in total

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