Literature DB >> 23591539

New advances in dual stereocontrol for asymmetric reactions.

Jorge Escorihuela1, M Isabel Burguete, Santiago V Luis.   

Abstract

Achieving dual stereocontrol in asymmetric reactions using a single enantiomer for the building of the chiral catalyst or auxiliary is a very important goal in enantioselective synthesis as it eliminates the need for having available the two enantiomers of the auxiliary or catalyst designed. Recent strategies and advances towards this goal during the last four years will be discussed throughout this review.

Year:  2013        PMID： 23591539     DOI： 10.1039/c3cs60068h

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN： 0306-0012            Impact factor:   54.564


  13 in total

1.  Asymmetric cross-dehydrogenative coupling enabled by the design and application of chiral triazole-containing phosphoric acids.

Authors:  Andrew J Neel; Jörg P Hehn; Pascal F Tripet; F Dean Toste
Journal:  J Am Chem Soc       Date:  2013-09-11       Impact factor: 15.419

2.  Enantioselective desymmetrization via carbonyl-directed catalytic asymmetric hydroboration and Suzuki-Miyaura cross-coupling.

Authors:  Gia L Hoang; Zhao-Di Yang; Sean M Smith; Rhitankar Pal; Judy L Miska; Damaris E Pérez; Libbie S W Pelter; Xiao Cheng Zeng; James M Takacs
Journal:  Org Lett       Date:  2015-02-02       Impact factor: 6.005

3.  Catalytic Enantioselective [3 + 2] Cycloaddition of α-Keto Ester Enolates and Nitrile Oxides.

Authors:  Samuel L Bartlett; Yoshihiro Sohtome; Daisuke Hashizume; Peter S White; Miki Sawamura; Jeffrey S Johnson; Mikiko Sodeoka
Journal:  J Am Chem Soc       Date:  2017-06-15       Impact factor: 15.419

4.  Enantioselective, Stereodivergent Hydroazidation and Hydroamination of Allenes Catalyzed by Acyclic Diaminocarbene (ADC) Gold(I) Complexes.

Authors:  Dimitri A Khrakovsky; Chuanzhou Tao; Miles W Johnson; Richard T Thornbury; Sophia L Shevick; F Dean Toste
Journal:  Angew Chem Int Ed Engl       Date:  2016-04-20       Impact factor: 15.336

5.  Dynamic control of chirality in phosphine ligands for enantioselective catalysis.

Authors:  Depeng Zhao; Thomas M Neubauer; Ben L Feringa
Journal:  Nat Commun       Date:  2015-03-25       Impact factor: 14.919

6.  Remarkably Facile Borane-Promoted, Rhodium-Catalyzed Asymmetric Hydrogenation of Tri- and Tetrasubstituted Alkenes.

Authors:  Veronika M Shoba; James M Takacs
Journal:  J Am Chem Soc       Date:  2017-04-17       Impact factor: 15.419

7.  Reagent-controlled enantioselectivity switch for the asymmetric fluorination of β-ketocarbonyls by chiral primary amine catalysis.

Authors:  Yang'en You; Long Zhang; Sanzhong Luo
Journal:  Chem Sci       Date:  2016-08-26       Impact factor: 9.825

8.  Enantiodivergent Steglich rearrangement of O-carboxylazlactones catalyzed by a chirality switchable helicene containing a 4-aminopyridine unit.

Authors:  Chien-Tien Chen; Cheng-Che Tsai; Pei-Kang Tsou; Gou-Tao Huang; Chin-Hui Yu
Journal:  Chem Sci       Date:  2016-08-25       Impact factor: 9.825

9.  A Stimuli-Responsive Rotaxane-Gold Catalyst: Regulation of Activity and Diastereoselectivity.

Authors:  Marzia Galli; James E M Lewis; Stephen M Goldup
Journal:  Angew Chem Int Ed Engl       Date:  2015-09-21       Impact factor: 15.336

10.  Central-to-Helical-to-Axial-to-Central Transfer of Chirality with a Photoresponsive Catalyst.

Authors:  Stefano F Pizzolato; Peter Štacko; Jos C M Kistemaker; Thomas van Leeuwen; Edwin Otten; Ben L Feringa
Journal:  J Am Chem Soc       Date:  2018-12-04       Impact factor: 15.419
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