| Literature DB >> 23521150 |
Roman Dobrovetsky1, Douglas W Stephan.
Abstract
Reaction of a 2:1 mixture of B(C6F5)3 and tBu3P with syn-gas results in the stoichiometric reduction of CO to give a formyl derivative which reacts further via an epoxy-borate intermediate to capture CO, affording a heterocylic alkoxyborate. Heating the reaction prompts reaction with H2 to give a borane-oxy-borate derivative, the product of C-O bond cleavage.Entities:
Year: 2013 PMID： 23521150 DOI： 10.1021/ja401492s
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419