Literature DB >> 23521074

N-formylation of amines by methanol activation.

Nuria Ortega1, Christian Richter, Frank Glorius.   

Abstract

The homogeneous catalyzed dehydrogenation of methanol in a synthetically valuable cross-coupling reaction was achieved. By the use of a simple ruthenium-N-heterocyclic carbene complex, MeOH and primary or secondary amines can be converted into formamides.

Entities:  

Year:  2013        PMID: 23521074     DOI: 10.1021/ol400639m

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  13 in total

1.  Oxidative Amide Coupling from Functionally Diverse Alcohols and Amines Using Aerobic Copper/Nitroxyl Catalysis.

Authors:  Paige E Piszel; Aristidis Vasilopoulos; Shannon S Stahl
Journal:  Angew Chem Int Ed Engl       Date:  2019-07-24       Impact factor: 15.336

2.  Catalyst free N-formylation of aromatic and aliphatic amines exploiting reductive formylation of CO2 using NaBH4.

Authors:  Arun Kumar; Pankaj Sharma; Nidhi Sharma; Yashwant Kumar; Dinesh Mahajan
Journal:  RSC Adv       Date:  2021-07-27       Impact factor: 4.036

3.  Synthesis of Formate Esters and Formamides Using an Au/TiO₂-Catalyzed Aerobic Oxidative Coupling of Paraformaldehyde.

Authors:  Ioannis Metaxas; Eleni Vasilikogiannaki; Manolis Stratakis
Journal:  Nanomaterials (Basel)       Date:  2017-12-12       Impact factor: 5.076

4.  Synergistic photocatalytic aerobic oxidation of sulfides and amines on TiO2 under visible-light irradiation.

Authors:  Xianjun Lang; Wan Ru Leow; Jincai Zhao; Xiaodong Chen
Journal:  Chem Sci       Date:  2014-10-30       Impact factor: 9.825

5.  Iron-catalyzed urea synthesis: dehydrogenative coupling of methanol and amines.

Authors:  Elizabeth M Lane; Nilay Hazari; Wesley H Bernskoetter
Journal:  Chem Sci       Date:  2018-04-09       Impact factor: 9.825

6.  A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol.

Authors:  María Andérez-Fernández; Lydia K Vogt; Steffen Fischer; Wei Zhou; Haijun Jiao; Marcel Garbe; Saravanakumar Elangovan; Kathrin Junge; Henrik Junge; Ralf Ludwig; Matthias Beller
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-02       Impact factor: 15.336

7.  Allylic alcohol synthesis by Ni-catalyzed direct and selective coupling of alkynes and methanol.

Authors:  Herong Chen; Zhijun Zhou; Wangqing Kong
Journal:  Chem Sci       Date:  2021-06-07       Impact factor: 9.825

8.  Hydrogen-borrowing and interrupted-hydrogen-borrowing reactions of ketones and methanol catalyzed by iridium.

Authors:  Di Shen; Darren L Poole; Camilla C Shotton; Anne F Kornahrens; Mark P Healy; Timothy J Donohoe
Journal:  Angew Chem Int Ed Engl       Date:  2014-12-09       Impact factor: 15.336

9.  Rhodium-catalyzed ketone methylation using methanol under mild conditions: formation of α-branched products.

Authors:  Louis K M Chan; Darren L Poole; Di Shen; Mark P Healy; Timothy J Donohoe
Journal:  Angew Chem Int Ed Engl       Date:  2013-11-29       Impact factor: 15.336

10.  Ruthenium-Based Catalytic Systems Incorporating a Labile Cyclooctadiene Ligand with N-Heterocyclic Carbene Precursors for the Atom-Economic Alcohol Amidation Using Amines.

Authors:  Cheng Chen; Yang Miao; Kimmy De Winter; Hua-Jing Wang; Patrick Demeyere; Ye Yuan; Francis Verpoort
Journal:  Molecules       Date:  2018-09-20       Impact factor: 4.411

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