Literature DB >> 23512489

Ammonia coordination introducing a magnetic moment in an on-surface low-spin porphyrin.

Christian Wäckerlin1, Kartick Tarafder, Jan Girovsky, Jan Nowakowski, Tatjana Hählen, Aneliia Shchyrba, Dorota Siewert, Armin Kleibert, Frithjof Nolting, Peter M Oppeneer, Thomas A Jung, Nirmalya Ballav.   

Abstract

Amazing ammonia: The molecular spin state of Ni(II) porphyrin, supported on a ferromagnetic Co surface, can be reversibly switched between spin-off (S = 0) and spin-on (S = 1) states upon coordination and decoordination of the gaseous ligand NH3, respectively (see picture). This finding clearly indicates the possible use of the system as a single-molecule-based magnetochemical sensor and in spintronics.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2013        PMID： 23512489     DOI： 10.1002/anie.201208028

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  5 in total

Review 1.  Porphyrins at interfaces.

Authors:  Willi Auwärter; David Écija; Florian Klappenberger; Johannes V Barth
Journal:  Nat Chem       Date:  2015-02       Impact factor: 24.427

2.  Vibrational fingerprint of localized excitons in a two-dimensional metal-organic crystal.

Authors:  M Corva; A Ferrari; M Rinaldi; Z Feng; M Roiaz; C Rameshan; G Rupprechter; R Costantini; M Dell'Angela; G Pastore; G Comelli; N Seriani; E Vesselli
Journal:  Nat Commun       Date:  2018-11-08       Impact factor: 14.919

3.  Achieving large thermal hysteresis in an anthracene-based manganese(II) complex via photo-induced electron transfer.

Authors:  Ji-Xiang Hu; Qi Li; Hai-Lang Zhu; Zhen-Ni Gao; Qian Zhang; Tao Liu; Guo-Ming Wang
Journal:  Nat Commun       Date:  2022-05-12       Impact factor: 17.694

4.  Disproportionation of Nitric Oxide at a Surface-Bound Nickel Porphyrinoid.

Authors:  Matus Stredansky; Stefania Moro; Manuel Corva; Henning Sturmeit; Valentin Mischke; David Janas; Iulia Cojocariu; Matteo Jugovac; Albano Cossaro; Alberto Verdini; Luca Floreano; Zhijing Feng; Alessandro Sala; Giovanni Comelli; Andreas Windischbacher; Peter Puschnig; Chantal Hohner; Miroslav Kettner; Jörg Libuda; Mirko Cinchetti; Claus Michael Schneider; Vitaliy Feyer; Erik Vesselli; Giovanni Zamborlini
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-21       Impact factor: 16.823

Review 5.  Stabilization and activation of molecular oxygen at biomimetic tetrapyrroles on surfaces: from UHV to near-ambient pressure.

Authors:  Erik Vesselli
Journal:  Nanoscale Adv       Date:  2021-02-01
  5 in total

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