Literature DB >> 23487537

Cu-ZSM-5: A biomimetic inorganic model for methane oxidation.

Pieter Vanelderen1, Ryan G Hadt, Pieter J Smeets, Edward I Solomon, Robert A Schoonheydt, Bert F Sels.   

Abstract

The present work highlights recent advances in elucidating the methane oxidation mechanism of inorganic Cu-ZSM-5 biomimic and in identifying the reactive intermediates that are involved. Such molecular understanding is important in view of upgrading abundantly available methane, but also to comprehend the working mechanism of genuine Cu-containing oxidation enzymes.

Entities:  

Keywords:  C-H activation; Cu-ZSM-5; Dicopper(II) oxo; Dioxygen activation; Model complex; Selective methane oxidation; Zeolite

Year:  2011        PMID： 23487537      PMCID： PMC3593946          DOI： 10.1016/j.jcat.2011.10.009

Source DB:  PubMed          Journal:  J Catal        ISSN： 0021-9517            Impact factor:   7.920


  39 in total

1.  Generation and reactions of organic radical cations in zeolites.

Authors:  Hermenegildo García; Heinz D Roth
Journal:  Chem Rev       Date:  2002-11       Impact factor: 60.622

2.  Oxygen precursor to the reactive intermediate in methanol synthesis by Cu-ZSM-5.

Authors:  Pieter J Smeets; Ryan G Hadt; Julia S Woertink; Pieter Vanelderen; Robert A Schoonheydt; Bert F Sels; Edward I Solomon
Journal:  J Am Chem Soc       Date:  2010-10-27       Impact factor: 15.419

3.  Bis(mu-oxo)dicopper as key intermediate in the catalytic decomposition of nitric oxide.

Authors:  Marijke H Groothaert; Kristof Lievens; Jeroen A van Bokhoven; Andrea A Battiston; Bert M Weckhuysen; Kristine Pierloot; Robert A Schoonheydt
Journal:  Chemphyschem       Date:  2003-06-16       Impact factor: 3.102

Review 4.  Reactivity of dioxygen-copper systems.

Authors:  Elizabeth A Lewis; William B Tolman
Journal:  Chem Rev       Date:  2004-02       Impact factor: 60.622

5.  A 1:1 copper-dioxygen adduct is an end-on bound superoxo copper(II) complex which undergoes oxygenation reactions with phenols.

Authors:  Debabrata Maiti; H Christopher Fry; Julia S Woertink; Michael A Vance; Edward I Solomon; Kenneth D Karlin
Journal:  J Am Chem Soc       Date:  2007-01-17       Impact factor: 15.419

Review 6.  Transition-metal ions in zeolites: coordination and activation of oxygen.

Authors:  Pieter J Smeets; Julia S Woertink; Bert F Sels; Edward I Solomon; Robert A Schoonheydt
Journal:  Inorg Chem       Date:  2010-04-19       Impact factor: 5.165

7.  Use of WO(4)(2-) on layered double hydroxides for mild oxidative bromination and bromide-assisted epoxidation with H(2)O(2).

Authors:  B F Sels; D E De Vos; P A Jacobs
Journal:  J Am Chem Soc       Date:  2001-08-29       Impact factor: 15.419

8.  Bis(mu-oxo)dicopper in Cu-ZSM-5 and its role in the decomposition of NO: a combined in situ XAFS, UV-vis-near-IR, and kinetic study.

Authors:  Marijke H Groothaert; Jeroen A van Bokhoven; Andrea A Battiston; Bert M Weckhuysen; Robert A Schoonheydt
Journal:  J Am Chem Soc       Date:  2003-06-25       Impact factor: 15.419

9.  Carboxylate binding in copper histidine complexes in solution and in zeolite Y: X- and W-band pulsed EPR/ENDOR combined with DFT calculations.

Authors:  Debbie Baute; Dafna Arieli; Frank Neese; Herbert Zimmermann; Bert M Weckhuysen; Daniella Goldfarb
Journal:  J Am Chem Soc       Date:  2004-09-22       Impact factor: 15.419

10.  A trinuclear intermediate in the copper-mediated reduction of O2: four electrons from three coppers.

Authors:  A P Cole; D E Root; P Mukherjee; E I Solomon; T D Stack
Journal:  Science       Date:  1996-09-27       Impact factor: 47.728
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  16 in total

Review 1.  Architecture and active site of particulate methane monooxygenase.

Authors:  Megen A Culpepper; Amy C Rosenzweig
Journal:  Crit Rev Biochem Mol Biol       Date:  2012-06-23       Impact factor: 8.250

2.  Perturbing the Copper(III)-Hydroxide Unit through Ligand Structural Variation.

Authors:  Debanjan Dhar; Gereon M Yee; Andrew D Spaeth; David W Boyce; Hongtu Zhang; Büsra Dereli; Christopher J Cramer; William B Tolman
Journal:  J Am Chem Soc       Date:  2015-12-22       Impact factor: 15.419

3.  Methane to acetic acid over Cu-exchanged zeolites: mechanistic insights from a site-specific carbonylation reaction.

Authors:  Karthik Narsimhan; Vladimir K Michaelis; Guinevere Mathies; William R Gunther; Robert G Griffin; Yuriy Román-Leshkov
Journal:  J Am Chem Soc       Date:  2015-02-02       Impact factor: 15.419

4.  Secondary Sphere Hydrogen Bonding in Monocopper Complexes of Potentially Dinucleating Bis(carboxamide) Ligands.

Authors:  Benjamin D Neisen; Pavlo Solntsev; Mohammad R Halvagar; William B Tolman
Journal:  Eur J Inorg Chem       Date:  2015-11-18       Impact factor: 2.524

Review 5.  Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.

Authors:  Courtney E Elwell; Nicole L Gagnon; Benjamin D Neisen; Debanjan Dhar; Andrew D Spaeth; Gereon M Yee; William B Tolman
Journal:  Chem Rev       Date:  2017-01-19       Impact factor: 60.622

6.  Electronic Structures and Reactivity Profiles of Aryl Nitrenoid-Bridged Dicopper Complexes.

Authors:  Kurtis M Carsch; James T Lukens; Ida M DiMucci; Diana A Iovan; Shao-Liang Zheng; Kyle M Lancaster; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2020-01-22       Impact factor: 15.419

7.  Evidence for oxygen binding at the active site of particulate methane monooxygenase.

Authors:  Megen A Culpepper; George E Cutsail; Brian M Hoffman; Amy C Rosenzweig
Journal:  J Am Chem Soc       Date:  2012-05-01       Impact factor: 15.419

8.  Access to a Cu(II)-O-Cu(II) motif: spectroscopic properties, solution structure, and reactivity.

Authors:  Peter Haack; Anne Kärgel; Claudio Greco; Jadranka Dokic; Beatrice Braun; Florian F Pfaff; Stefan Mebs; Kallol Ray; Christian Limberg
Journal:  J Am Chem Soc       Date:  2013-10-17       Impact factor: 15.419

9.  Improved Efficiency for Partial Oxidation of Methane by Controlled Copper Deposition on Surface-Modified ZSM-5.

Authors:  Thomas Sheppard; Helen Daly; Alex Goguet; Jillian M Thompson
Journal:  ChemCatChem       Date:  2015-12-04       Impact factor: 5.686

10.  Hydroxo-bridged dicopper(II,III) and -(III,III) complexes: models for putative intermediates in oxidation catalysis.

Authors:  Mohammad Reza Halvagar; Pavlo V Solntsev; Hyeongtaek Lim; Britt Hedman; Keith O Hodgson; Edward I Solomon; Christopher J Cramer; William B Tolman
Journal:  J Am Chem Soc       Date:  2014-05-12       Impact factor: 15.419
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